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Predict the major product and show correct stereochemistry 3-12 11 CH3CCI Meo -NO2 AICI: 3-13 1)...
Predict the major product expected in each of the following
reactions. Clearly show stereochemistry in your drawing, if
applicable.
ŞOH H2SO4 (diluted) heating 1CH,CHSCVAICI, 2) Zn(Hg)/HCI он BryFeBry ထိ Sot KMnO4 H, heat CH3CCI Meo -NO2 AICI, 1) Fuming H2SO4 2) SOCI AICI
draw the major product
11. Ç(CH3) 30 1) CH3CCI, AICI 2) (CH3)2NH H2, Raney-Ni, heat 12. ÇO Me 1) PhMgBr (2 equiv.) 2) H20, H,00 13. CNH2 1) Brz, NaOH, H20 O 11 2) CH3CCI, pyridine
give major product
O 11. Ç(CH3)3 1) CH3CCI, AICI: 2) (CH3)2NH H2, Raney-Ni, heat 12. ÇO Me 1) PhMgBr (2 equiv.) 2) H20, H30 13. CNH2 1) Brz, NaOH, H20 2) CH,CCI, pyridine 14. HNO3 CHO но +н н+он н+он нон CH OH оо 15. H2NCO, 1) (CH3),COCOCOC(CH3)3 Ph -N: C: NH- PhNHNH | 16. CHO HOTH HOH (3 equiv.) H-OH HO+H CH2OH ai
draw the major
product/s of each of these reacifons
10. AICI: CI 11. NO2 I CI AICI: ay 12.
4. (12 marks) For each of the following reactions, predict the
MAJOR product with correct stereochemistry.
4. (12 marks) For each of the following reactions, predict the MAJOR product with correct stereochemistry. NaSCH3 CH3SH (b) - Se(CH3)2 DMF SelfH3)2, con "ayam HD M NaOH sH - hint: product has a S atom in a ring (d) ethanol fone come NaCN acetone CH3 ci+H 1 eq. NaN3 DMSO HOH CH3
9. UI НО, HNO3 / H2SO4 10. AICI: CI 11. NO2 CI AICI: X 12.
For
each reaction predict the product. If isomers are possible only
show the major product.
H3C Br SO3 H2SO4 ("fuming') AICI HNO3 a) c) H3C H2SO4 Cl d) CH3 (internal F-C AICl3 alkylation) H3C
Predict the major product of the following reactions.
AICI 1. NBS, light 2. NaCN NO2 NaOCH2CH3
Question 10 5 pts What is the major organic product obtained from the following reaction? HNO3 H2SO4 NO2 NO2 NO2 NO2 11 - IV O! Oll OIHI OTV Question 13 5 pts What is the major organic product obtained from the following reaction? AICI, CI doooooo Ol Ol O III O IV D Question 14 5 pts What is the product of the following reaction? KMnO4 H2O OH III IV 01 OHI O III IV D Question 20 5 pts...
find major product for each
O Ç(CH3)3 1) CH3CCI, AICI = 2) (CH3)2NH H2, Raney-Ni, heat CO2Me 1) PhMgBr (2 equiv.) 2) H20, H30*