Question


Calculate ΔG° for the electrochemical cell Pb(s) | Pb2+(aq) || Fe3+(aq) | Fe2+(aq) | Pt(s).

A) –1.2 x 102 kJ/mol

B) –1.7 x 102 kJ/mol

C) 1.7 x 102 kJ/mol

D) –8.7 x 101 kJ/mol

E) –3.2 x 105 kJ/mol


Table 18.1 Standard Reduction Potentials at 25°C. E(V) +2.87 +2.07 +1.82 Half-Reaction F,(g) + 2e-→ 2F-(aq) 03(g) + 2H(aq) + 2e-_→O2(g) + H2O Co3+(aq) + e-_ Co2+(aq) H2O2(aq) + 2H+(aq) + 2e-_→ 2H2O PbO (s) 4H(aq)SO (a) 2ePbSO4(s) 2HO Ce4+(aq) + e-_→ Ce3+(aq) MnO4 (aq) + 8H+(aq) + 5e-→ Mn2 + (aq) + 4H20 Au3+ (aq) + 3e-→ Au(s) Cl2(g) + 2e-→ 2C1-(aq) Cr202-(aq) + 14H(aq) + 6e-→ 2Cr(aq) + 7H20 MnO2(s) + 4H(aq) + 2e-_→ Mn2+(aq) + 2H2O 02(g) + 4H(aq) + 4e-_→ 2H20 +1.70 +1.61 +1.51 +1.50 +1.36 +1.33 +1.23 +1.23 +1.07 +0.96 +0.92 +0.85 +0.80 +0.77 +0.68 +0.59 +0.53 +0.40 +0.34 +0.22 +0.20 +0.15 +0.13 0.00 -0.13 -0.14 -0.25 -0.28 -0.31 -0.40 -0.44 -0.74 -0.76 -0.83 NO3 (aq) + 4H (aq) + 3c-→ NO(g) + 2H2O 2Hg2 +(aq) + 2e-→ Hg.(aq) Hel(aq) + 2e → 2Hg(1) Ag (aq) eAg(s) Fe3+(aq) + e Fe2+(aq) 0 (8) +2H (a)2eH,O2(aq) MnO4(aq) + 2H2O 3eMnO2(s) +40H (aq) -12(s) + 2e- 21-(aq) -Cu2+(aq) + 2e-→ Cu(s) 듦 soi-(aq) + 4H(aq) + 2e-→ SO2(g) + 2H2O 。sn(aq) + 2e- Sn2+(aq) 02(g) + 2H2O + 4e-_→ 40H(aq) AgCl(s) + e-_ → Ag(s) + Cl-(aq) Cu2+(aq) + e → Cu(aq) 2H(aq) + 2e H2(g) Pb2+(aq) + 2e → Pb(s) S㎡+(aq) + 2e-→ Sn(s) Ni2+(aq) + 2e-_→ Ni(s) Co2+(aq) + 2e-→ Co(s) PbSOds) + 2e-→ Pb(s) + S01-(aq) Cd2+(aq) + 2e → Cd(s) Fe2+(aq) + 2e-→ Fe(s) Cr3+(aq) + 3e-→ Cr(s) Zn2+(aq) + 2e → Zn(s) 2H2O + 2e-_→ H2(g) + 20H(aq) Mn2+(aq) + 2e → Mn(s) Al3+(aq) + 3e-→ Al(s) Be2 (aq) 2eBe(s) Mg2+(aq) + 2e → Mg(s) Na+(aq) + e-_ → Na(s) Ca2+(aq) + 2e-→ Ca(s) sr(aq) + 2e-→ Sr(s) Ba2+(aq) + 2e Ba(s) K (aq)e K(s) Li+(aq) + e-→ Li(s) -2.37 -2.87 -2.89 -2.90 -2.93 -3.05

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