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Calculate AG and K at 25°C for the reactions. a. 7H,0 + 2 Cr3+ + 3Cl2...
Consider the following cell reaction at 18°C: Ca(e)+Cu+ (aq) + Ca2+ (aq) + Cu() Calculate the standard cell potential of this cell from the standard electrode potentials, and from this, obtain AG" for the cell reaction. Calculate AF. Use these values of AN and AG to obtain AS for the cell reaction. Ca²+ (aq) +20 + Ca() --2.76 V Cu? (g) +20 + Cu(s) - 0.84 V AH;(O.*()) -- 542.8 kJ/mol AH;(Out (as)) - 64.8 kJ/mol V AG- AH- kJ...
Calculate the standard Gibbs free energy changes at 25 °C for each of the reactions shown below using the Eº values given. Select whether each of these reactions is nonspontaneous, at equilibrium, or spontaneous under standard conditions. (a) 2 Lit(aq) + 2 I'(aq) = 2 Li(s) + 1 12(5) ° = -3.586 V AGC= X kJ/mol nonspontaneous at equilibrium spontaneous (b) 2 CO3+ (aq) + 1 Hg(0) = 2 Co2+ (aq) + 1 Hg2+(aq) ° = 0.988 V AGº =...
Calculate Eº and K at 25°C for ,02-(aq) +Cr2+ (aq) → Cr3+(aq) + 5,032-(aq) half reactions are 8,062-(aq) + 2e → 28,0,2-(aq), E° = 0.17 V Cr3+ (aq) + e + Cr2+(aq), E° = -0.50 V
Calculate AG for the following reaction at 25°C. 2 Ca(s) + O2(g) → 2 Ca(s) (J/K mol) Substance AH (kJ/mol AG (kJ/mol) Ca(s) Ca2+(aq) CaO(s) Ca(OH)2(5) CaF2(5) CaCl(s) O(g) 028) O3(aq) Oz(8) -542.96 -635.6 -986.6 -1,214.6 -794.96 249.4 -553.0 -604.2 -896.8 -1,161.9 -750.19 230.1 41.6 -55.2 39.8 83.4 68.87 113.8 160.95 205.0 110.88 237.6 -12.09 142.2 16.3 163.4
For all of the following
experiments, under standard conditions, which species could be
spontaneously produced?
A lead wire is placed in a solution containing
Cu2+
yes no Cu
yes no PbO2
yes no No reaction
Crystals of I2 are added to a solution of
NaCl.
yes no I-
yes no No reaction
yes no Cl2
A silver wire is placed in a solution containing
Cu2+
no yes Cu
no yes No reaction
no yes Ag+
Half-Reaction 8° (V) Half-Reaction 8° (V) 2.87 1.99 1.82 1.78 1.70 1.69 1.68 1.60...
1. How do I read the half reaction table?
2. If im asked for the best reducing agent from Cu+, Ag+, F2, and
Fe3+, where do I look first in the table? before the arrow or after
the arrow?
3. Sometimes a value that has originally a positive (V) from the
table it will have the negative sign in a homework problem, and
viceversa, so the question is, how do I use the positive and
negative signs in respect to...
Find the best reducing agent from Cu+, Ag+ F2 and Fe3+
#1. In the reduction table i can see several repeated values of
Fe3+ one is equal to 0.77v and the second one is equal to -0.036v
so, which one do I choose? Please explain.
#2.If I'm asked to find the best oxidation agent, from the
values already provided (Cu+, Ag+ F2 and Fe3+) which one would it
be? and how would I decide from repeated values, like in #1,...
AG°= AH-TAS AG=AGº+RTinQ where R=8.314 J/mol K 1. Calculate AGº for the following reaction at 25 °C if AH°= -1854 kJ/mol; AS°= -236 J/mol K CH-COCH3(g) + 402(g) → 3C02(g) + 3H2O(1) 2. NH.NO, dissolving in water is a spontaneous process. As it dissolves, the temperature of the solution decreases. Based on this, what must the signs (positive or negative) of AG, AH, and AS be?
E sul Usi G ". and K 33. Calculate AG"and K at 25°C for cell reactions in which 2 = 3 and E is: a. 0.00 V b . +0.500 V c.-0.500 V ion cen
2. Using the decay chain for 238U, calculate the amount of time it takes 5.0 kg of 238U to decay to 2.5 kg. What mass of 206Pb is produced? (5 points) (V) Helpful Stuff Thermodynamics: AG° = AH-TAS Nernst Equation: 6 = 6 - (RT/nF)InQ AG=RTIK At 25°C: 8 = 6 - (0.0591/n)logQ ΔGIRT Ke=e AGⓇ = -nF8° Units/Constants: Volt: 1 V=1/C Faraday: 1 F -96,485 C/mol e Arrhenius Equation: k = Ae Ea/RT R= 8.314 J/mol K Integrated Rate...