show mech warm and conc On 13. Ozonolysis CH-S-ch Practice problems: CH-S-CH CH3-S-CH3 pro rnctice Problems:...
13. Complete the following reactions CH3CH2=CH-CH3 + Br2® CH3CH2=CH-CH3 + HIⓇ CH3CH2=CH-CH3 + H2O® 14Name the following compounds. Naz[CO(NH3)2C14] [Co(en)3]3+ Li3[AlF6]
3. Complete the following reactions. HBr conc. H2SO4 2-methyl-2-pentanol (CH)CO Na (CH3)COH РСС (1) BH3-THF (2) H2O2, OH ionard.
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CH3 H2O + 1. H-C-CH-CH-CH2 CH3 CH C 2, CHy-CH2-CH-CHOHPCC 25°C 50-55°C + HNO H2SO4 он H2CrO4 CH,CHCH acetone, 35°c Et O 2150113H20 5. CH3(CH2)2MgBr+ CH3(CH2)sC(CH2)sCH3 Nall CH2-CHCH2l H2SO4 140°C 6. CH3CH2CH2OH 7. CHCH CHOH 1) LiAIH(O-t-Bu)3,-78°C 2) H20 8. CH,C-CI HBr 9. CH2 CH-CH-CH2 40°C 10. H3C CIH2 Benzene 100℃ H3C 1. LiAIH/Et2O 11. CH,CH2CH,COH 2. H,0 12. + CH,CH,cCI AIC Benzene, 80°C 13. Br2 heat CH3 AlcI 15. 25°C conc. H2SO4 NaBH4...
Predict the major product(s) from the following
reactions:
CH3 CH₃ H₃C H₂ ? -CH₃ CH3 НАС 1. BH3-THF 2. H2O2, NaOH ? CH3 Brz CH3 CH2OH
Predict the major product(s) from the following reactions.
CH3 CH3 Нас CH
Problem #1 Predict the major product(s) from the following reactions: CH3 1. 03 ? 2. DMS b) CH₃ H₂C 1. CH2CO3H 2. H3O+ CH3 CH3 HC 1. BH3-THF 2. H2O2. NaOH CH Extra Credit An unknown compound A of molecular formula of C10H180 reacts with H2SO4 and heat to form two compounds (B and C) of molecular formula C10H16. B and C both react with H2 over Pd/C to form decalin. Ozonolysis of B forms D, and ozonolysis of C...
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (S1, S2, E1, or E2) of each reaction KOC(CH) CH:CH-CH:CH BY (CH3),COH, 82°C 9 CH CH CH CH Br Na SCH CH,OH,0°C Nå SCH.CH DMF, 0°C 4 CHI - NaNO, sc CH CH3-Cors HO 22°C CH CH CH,OH 22°C K®SC(CH3) (CH3),COH, 82°C CHẠI • CH,SH 43°C масH,CH, CH,CHOH, 78°C CH H20 22°C Nясн, CH,OH, 0°C
Problems 101 2 CH-CH-CH-S-CH-CH-CH, A CH, CH3)4CH, SH B CH, -CH-CH:-0-CH-CH2-CH, CH-CH-CHU-0 H с D HUMBERS 6. The infrared spectra of some polymeric materials follow. Assign a structure to each of them, selected from the following choices: polyamide (nylon), poly(methyl methacrylate), polyethylene, polystyrene, and poly(acrylonitrile-styrene). You may need to look up the structures of these materials. MORO 14 200 2000 9900 1400 1200 WAVENUVIDERSION) 1000 MICRONS 1 12 13 14 15 TRANSMITTANCE man 1730 cm 1600 1200 1000 600 WAVENUMBERS
Predict the product(s) from the following reactions:
e) CH3 CH₃ - H₂C~ H₂ ? a ~CH₂ 1 H₃ C CH3 1. BH2-THF CH3 2. H2O2, NaOH Br2 CH3OH CH,
Draw the product(s) of the following reactions 1. ВНз / THF CH-CH-CH2-CEС-CH-CH-CH3 2. H202/ aqueous NaOH