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2. Nitrilotriethylamine, N(CH2CH2NH2)3 is a multidentate ligand. (a) What is the maximum number of binding (Lewis...

2. Nitrilotriethylamine, N(CH2CH2NH2)3 is a multidentate ligand.

(a) What is the maximum number of binding (Lewis base) sites which are present for nitrilotriethylamine to bind to a metal ion in an aqueous solution? When it binds with Cu2+, what is the number of nitrilotriethylamine used per each Cu2+?

(b) If a 50.00 mL Cu2+ solution needs 100.0 mL, 0.0100 M N(CH2CH2NH2)3 to react with, calculate the molar concentration of the original Cu2+ solution.

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Answer #1

(a) Nitrilotriethylamine, N(CH2CH2NH2)3 is a tetradentate ligand.

The maximum number of binding (Lewis base) sites which are present for nitrilotriethylamine is 4.

The number of nitrilotriethylamine used per each Cu2+ is 1 [Cu(tren)2L]2+.

(b)

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