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2) Provide the missing information in the following sequences Pd /H2 HF Starting C) Material Product...
2. Fill in the missing reagent, product or catalyst. H2, Pd/C A. excess) CH2l2, Zn(Cu) B. ether HIO4 C. H20, THF 2) NaHSO3
6. Supply the missing starting material, product(s) or reagent(s) for the following reactions. Show the stereochemistry where applicable: /10 Lindlar catalyst + H2 = + Cl2 1 mol H + 2HCI Er +
Starting Material Reagent Major Product? H2, Pd/C 1) 050 2) aq. KHSO3 1) CH3CO3H 2) NaOH/H20 Braz/H20 1) 0; 2) Zn/HOÁC Provide reagents and/or starting materials to accomplish the following transformations pH ن – EC–CH = ا سے ہی الا) CH3 0CH3 H.C ) م any alkene CH3 H3C- Hy, Pd/C CH3 optically active diterpene mixture of diastereomers 1) 0, 2) Zn/HOÁC нэс CH3 + 0 + 0 + H нас
Starting Material Reagent Major Product? H2, Pd/C 1) OsO4 2) aq. KHSO: 1) CH3CO3H 2) NaOH/H20 Bra/H20 1) O3 2) Zn/HOÁC Provide reagents and/or starting materials to accomplish the following transformations. 40 OH –c=C=CH- CH3 CH3 -оснэ Онон H3C CH3 он any alkene CH₃ CH₂ HC- H.Pd/C optically active diterpene CH mixture of diastereomers 1) O 2) ZHOÁC H3C H3C CH3 + Hн H3c1
Starting Material Reagent Major Product? H2, Pd/C 1) Os04 2) aq. KHSO3 1) CH3CO3H 2) NaOH/H20 Brz/H2O 1) O3 2) Zn/HOÁC
Provide the missing reagent for the reaction below. Eto (A) H2, Pd/C (C) LOAIHA (B) KMnO4, H20, 100 °C (D) Na, NH3(1), MeOH
1. Provide the missing starting material, reagents, or major organic product for each of the following reactions. (No more than two steps are required in any case where we ask you to fill in reagents.) 1. Mgo, Et20 2. H20 a) Cl b) MgBr OH , Et20 2. H* workup c) OH d) NaOH (cat.) e) OH NaBH4, CeCl3, MeOH
1) How can the following product be prepared using ethyne as the starting material? 2) What are the products of the following reactions? (6 points) Cla excess b) H2 Lindlar catalyst c) HBO excess
Starting Material Reagent Major Product? H2, Pd/C 1) OsO4 2) aq. KHSO3 1) CH3CO3H 2) NaOH/H20 Brz/H20 1) 03 2) Zn/HOÁC
Trans 2-pentene Glyceraidehyde Acetone H2 2. Provide the major product for the following reactions. The starting material and the conditions and the type of reaction are all given + Reactants → DEHYDRATION + H' and heat он Citronelloll B) HYDRATION catalytic H+ → and HOH Citronella oil C) OXIDATION Citronella oil (using Benedict's reagent) D) HYDROGENATION REDUCTION + catalytic Pd → Citronella oil and H2 DECARBOXYLATION heat→ E) OH 3 Provide the following