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3. The reaction of the anti-cancer drug cisplatin with water is Pt(NH3):C12(aq) + H20(I) → Pt(NH3)2(H2O)Clı"(aq)...
2) Reaction of the anti-cancer drug cisplatin (Pt(NH3)2Cl2) with water is described by the following equation:...
2) Reaction of the anti-cancer drug cisplatin (Pt(NH3)2Cl2) with water is described by the following equation: Pt(NH3)2Cl2 (aq) + H2O (l) Pt(NH3)2(H2O)Cl+ (aq) + Cl- (q) The rate of this reaction increases by a factor of 15 on raising the temperature from 25oC to 50oC. What is the value of the activation energy in kJ/mol? (3 marks)
The chemotherapy drug cisplatin (Pt(NH3)2Cl2) is made by the following reaction: (NH4)2PtCl4 (s) + NH3 (aq)...
The chemotherapy drug cisplatin
(Pt(NH3)2Cl2) is made by the
following reaction:
(NH4)2PtCl4 (s) +
NH3 (aq)
NH4Cl (aq.) +
Pt(NH3)2Cl2 (s)
The reaction is not balanced. If you start with 20.0 g of
(NH4)2PtCl4 and 2.00 g of
NH3, which reagent is in excess and which reagent is the
limiting reagent. Please show plan and set up.
(e) In the reaction: H202(a) +3 (a)+ 2 H(a)Is (a)+ 2 H2O( (aq) (aq)13 3 (aq) the concentration of I- decreases from 0.1...
(e) In the reaction: H202(a) +3 (a)+ 2 H(a)Is (a)+ 2 H2O( (aq) (aq)13 3 (aq) the concentration of I- decreases from 0.173 to 0.146 mol dm-3 in 1 min. What is the rate of the reaction over this time interval? [2 marks (f) The activation energy for the formation of ethane from cyclobutane is 260 kJ mol1. If the rate constant at 300°C is 7.9 x 10 9 s-1, what is the pre-exponential factor A for this reaction? 12...
The enzyme carbonic anhydrase catalyzes the reaction CO2(g)+H2O(l)−→−HCO3−(aq)+H+(aq).CO2(g)+H2O(l)→ HCO3−(aq)+H+(aq). In water, without the enzyme, the reaction...
The enzyme carbonic anhydrase catalyzes the reaction CO2(g)+H2O(l)−→−HCO3−(aq)+H+(aq).CO2(g)+H2O(l)→ HCO3−(aq)+H+(aq). In water, without the enzyme, the reaction proceeds with a rate constant of 0.039s−10.039 s−1 at 25°C.25 °C. In the presence of the enzyme in water, the reaction proceeds with a rate constant of 1.0×106s−11.0×106 s−1 at 25°C.25 °C. Assuming the collision factor is the same for both situations, calculate the difference in activation energies for the uncatalyzed versus enzyme- catalyzed reaction.
Ammonia (NH3) reacts with oxygen (O2) to form nitric oxide (NO) and water (H20). Consider the...
Ammonia (NH3) reacts with oxygen (O2) to form nitric oxide (NO) and water (H20). Consider the reaction of 100 moles/s of ammonia at 25°C with 50% excess air also at 25°C. The reaction reaches 75% conversion of the limiting reagent and the products leave at 200°C. The entire process is conducted isobarically at 1 atm. Determine the following: a) Write down the balanced chemical reaction per mole of the limiting reagent? (6 pts) b) What are the initial amounts of...
3. i). Write the formula of four strong acids and four strong bases. ii). List four...
3. i). Write the formula of four strong acids and four strong bases. ii). List four factors that affect the strength of an acid. iii). Predict the relative strength of the following compounds: H2O, H2S and H2Se. iv). Which of the following is the stronger acids: CHCICOOH or CHCI-COOH? Explain. v). Al 3* is not a Bronsted acid, Al(H2O)" is. Explain. vi). All Bronsted acids are Lewis acids, but the reverse is not true. Give two examples of two Lewis...
Sodium hydroxide reacts with carbon dioxide as follows: 2 NaOH(s) + CO2(g) Na2CO3(s) + H2O(1) If...
Sodium hydroxide reacts with carbon dioxide as follows: 2 NaOH(s) + CO2(g) Na2CO3(s) + H2O(1) If 3.70 mol NaOH and 2.00 mol CO2 are allowed to react, how many moles of the excess reactant remains? 0.15 mol CO2 O 0.30 mol NaOH O 1.70 NaOH 1.00 mol CO2 How much energy is required to change the temperature of 1.50 L of water from 25.0 °C to 100.0 °C? The specific heat capacity of water is 4.184 J/g.°C; density H2O =...
1) The rate constant for the reaction 2 N,Os(9) = 4 NO (9) + O2(9) is...
1) The rate constant for the reaction 2 N,Os(9) = 4 NO (9) + O2(9) is reported in units of sl. What is the overall order of the reaction? 2) The rate law for a reaction was reported as rate=k[A] [B][C] with molar concentrations in moles per cubic decimetre and time in seconds. What are the units of k? 3) The rate constant for the pseudo first-order acid- catalysed hydrolysis of glucose is 4.07' 10-s. Calculate the half-life for the...
Homework #7A Name: Due date: 3-16-20 1. How many moles of water, H20, contain 9.03 *...
Homework #7A Name: Due date: 3-16-20 1. How many moles of water, H20, contain 9.03 * 10molecules of water? 2. How many molecules are present in 4.9 moles of L,CO3. 3. How many moles of oxygen are present in 4.9 moles of L.COM 4. How many Li atoms are in 4.5 moles of Li? 5. Calculate the mass, in grams, for 3.75 10 molecules of C2Hs. 6. Calculate the mass, in grams, for 3.5 moles of CHO. 7. Calculate the...
i need help asap. i need this in less then an hour and my grade depends...
i need help asap. i need this in less then an hour and my
grade depends on it please help. i would really appreciate the help
thank you so much
8. 300 250 200 150 PE (kJ) 100 50 0 Progress of the reaction Which of the following are the values for the activation energy (E.) and change in enthalpy (AH) for the reverse reaction? A. 300 -50 B. 150 +50 C. 100 -50 D. 100 +50 Use the following...
The chemotherapy drug cisplatin
(Pt(NH3)2Cl2) is made by the
following reaction:
(NH4)2PtCl4 (s) +
NH3 (aq)
NH4Cl (aq.) +
Pt(NH3)2Cl2 (s)
The reaction is not balanced. If you start with 20.0 g of
(NH4)2PtCl4 and 2.00 g of
NH3, which reagent is in excess and which reagent is the
limiting reagent. Please show plan and set up.
(e) In the reaction: H202(a) +3 (a)+ 2 H(a)Is (a)+ 2 H2O( (aq) (aq)13 3 (aq) the concentration of I- decreases from 0.173 to 0.146 mol dm-3 in 1 min. What is the rate of the reaction over this time interval? [2 marks (f) The activation energy for the formation of ethane from cyclobutane is 260 kJ mol1. If the rate constant at 300°C is 7.9 x 10 9 s-1, what is the pre-exponential factor A for this reaction? 12...
Ammonia (NH3) reacts with oxygen (O2) to form nitric oxide (NO) and water (H20). Consider the reaction of 100 moles/s of ammonia at 25°C with 50% excess air also at 25°C. The reaction reaches 75% conversion of the limiting reagent and the products leave at 200°C. The entire process is conducted isobarically at 1 atm. Determine the following: a) Write down the balanced chemical reaction per mole of the limiting reagent? (6 pts) b) What are the initial amounts of...
3. i). Write the formula of four strong acids and four strong bases. ii). List four factors that affect the strength of an acid. iii). Predict the relative strength of the following compounds: H2O, H2S and H2Se. iv). Which of the following is the stronger acids: CHCICOOH or CHCI-COOH? Explain. v). Al 3* is not a Bronsted acid, Al(H2O)" is. Explain. vi). All Bronsted acids are Lewis acids, but the reverse is not true. Give two examples of two Lewis...
Sodium hydroxide reacts with carbon dioxide as follows: 2 NaOH(s) + CO2(g) Na2CO3(s) + H2O(1) If 3.70 mol NaOH and 2.00 mol CO2 are allowed to react, how many moles of the excess reactant remains? 0.15 mol CO2 O 0.30 mol NaOH O 1.70 NaOH 1.00 mol CO2 How much energy is required to change the temperature of 1.50 L of water from 25.0 °C to 100.0 °C? The specific heat capacity of water is 4.184 J/g.°C; density H2O =...
1) The rate constant for the reaction 2 N,Os(9) = 4 NO (9) + O2(9) is reported in units of sl. What is the overall order of the reaction? 2) The rate law for a reaction was reported as rate=k[A] [B][C] with molar concentrations in moles per cubic decimetre and time in seconds. What are the units of k? 3) The rate constant for the pseudo first-order acid- catalysed hydrolysis of glucose is 4.07' 10-s. Calculate the half-life for the...
Homework #7A Name: Due date: 3-16-20 1. How many moles of water, H20, contain 9.03 * 10molecules of water? 2. How many molecules are present in 4.9 moles of L,CO3. 3. How many moles of oxygen are present in 4.9 moles of L.COM 4. How many Li atoms are in 4.5 moles of Li? 5. Calculate the mass, in grams, for 3.75 10 molecules of C2Hs. 6. Calculate the mass, in grams, for 3.5 moles of CHO. 7. Calculate the...
i need help asap. i need this in less then an hour and my
grade depends on it please help. i would really appreciate the help
thank you so much
8. 300 250 200 150 PE (kJ) 100 50 0 Progress of the reaction Which of the following are the values for the activation energy (E.) and change in enthalpy (AH) for the reverse reaction? A. 300 -50 B. 150 +50 C. 100 -50 D. 100 +50 Use the following...
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