ame Seat: Organic Chem 141-03 2018 Dec 4 Name 2. Five IR spectra are shown on...
IR spectroscopy 1. Match the following six compounds to the IR spectra shown below. Draw the structure in the box. On the spectra, mark all important peaks with arrows or circles, and label them with corresponding bonds. NH2 orte de Structure: IR Spectrum lould film) 1723 V 4000 2000 3000 1200 1600 V (cm ) Structure: IR Spectrum fiquld fam) 4000 2000 V (cm 16001200800 ) Exp - 119- Exp. 100 Structure: 3600-2500 IR Spectrum liguld fm) U 1715 4000...
IR Worksheet-CHEM 2460 Spectrum A- Fare the IR spectra of the compounds shown, In Spectrum A-F, assign the major absorptions above 1500 em in the spectrum of each compound, (using and 8 2 [see background informationD) A. IR spectra of phenylethyne 100 80 40 20- 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200 1000800 Wavenumber (cm) IR spectra of n-butyl acetate 100 B. 80 60 40 CHsCO(CH2)30% 20 4000 3600 3200 2800 2400 2000 1800 1600 1400 1200...
Label the spectra and propose a structure for the compound.
Compound 4 IR Spectrum hould 4000 3000 17000 2000 2000 V (cm 1600 ) 1200 800 Mass Spectrum TTTTTTTT Sofhose pas No significant UV absorption above 220 mm M 100 CHOO 0 120 180 200 200 200 13C NMR Spectrum (1000 MHCOCI, solution DEPT CHICK CH proton decoupled 200 160 120 80 40 0 (ppm) "H NMR Spectrum (400 MHE. CDC, solution 10 9 8 7 6 5 4 3...
Deduce the following structure of the compound given their IR, H1
NMR, 13C NMR spectra, and assign IR functional group absorptions
and assign the structure's protons and carbons to their respective
spectral resonances.
Compound 6 1756 IR Spectrum uid Sm) 15820 4000 3000 2000 1600 1200 800 V (cm) 100 55 Mass Spectrum 71 80 70 60 No significant UV M158 (1%) absorption above 220 nm C&H140s 40 80 120 160 200 240 280 m/e 13C NMR Spectrum (50.0 MHz,...
Deduce the structure based on the information below:
Concepts: organic spectroscopy, organic chemistry
Problem 52 IR Spectrum (Tiquid film) t760 U 4000 3000 1200 800 2000 V (cm 1600 ) Mass Spectrum TTTTTTTTTT % of base peak No significant UV absorption above 220 mm 87 M+* = 146 (<1%) LLLLLLLLLLLL 40 80 120 160 m/e 200 240 280 13C NMR Spectrum (20.0 MHz, CDCI, solution) solvent proton decoupled www pornowww 200 160 120 80 40 0 8 (ppm) 1H NMR...
Deduce the structure based on the information below:
Concepts: organic spectroscopy, organic chemistry
- Problem 53 IR Spectrum (liquid film) 4000 3000 1600 1200 . 800 2000 V (cm Mass Spectrum % of baso peak No significant UV absorption above 220 nm 115 M+ 146 40 80 200 240 120 160 m/e 280 13C NMR Spectrum (50.0 MHz, CDC, solution) solvent proton decoupled 200 160 120 80 40 0 8 (ppm) TH NMR Spectrum (200 MHZ, CDCI, solution) TMS LIIIIIIIIIIIIIIIII...
Deduce the structure based on the information below:
Concepts: organic spectroscopy, organic chemistry
Problem 69 2288 IR Spectrum (liquid film) 4000 3000 1200 800 2000 V (cm 1600 ) Mass Spectrum 88 TTTTTTTTTTT % of base poak No significant UV absorption above 220 nm M+ = 94 < 1%) 40 80 160 200 240 280 120 m/ 13C NMR Spectrum (20.0 MHz, CDCI, solution) TMS solvent prolon decoupled 200 160120 80 40 0 8 (ppm) 1H NMR Spectrum (100 MHz,...
Determine the structure of the molecule with formula CeH,OCI from the following spectra and explain your reasoning: 3. 875 1773 1738 IR Spectrum (liquid film) 800 2000 ,1600 1200 V (em1) 3000 4000 13C NMR Spectrum 100.0 MHz, CDA, solutanj 132 13t ppm preien decoupled r82 131 Dpmsolent 160 200 120 80 40 δ(ppm) 0 H NMR Spectrum (ad0 MH2. COc soution) exparslon 80 7.5 7.0 ppm TMS 10 9 87 654 3 2 1 δ (ppm)
Give a short written description for all sections (eg. IR,
C-NMR, H-NMR, Mass Spec ,any chemical tests described, MW or
elemental analysis). Compile data from sections to propose a
chemical structure for the unknown.
IR Spectrum 2987 (liquid film) 800 1600 1200 2000 3000 4000 v Cm Mass Spectrum 100 80 60 8 40F5 M+ 122/124 20 3 17 40 80 120 160 2000 240 280 m/e problem 7 No significant UV absorption above 220 nm
Please help me annotate the
following spectra.
"roblem 4 3396 3334 IR Spectrum 1662 4000 3000 1200 800 2000 v (cm 1600 ) 120 Mass Spectrum Provide the structure for the problem in the space provided % of base peak M+ 135 Cg H, NO 40 80 120 160 m/e 200 240 280 Students are to ignore marked solvents and water in NMR spectra. 13C NMR Spectrum (100 Mz, DMSO-d6 solution) DEPT CHA CHA CHA solvent proton decoupled 200 160...