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57.) The ozone, O3, of the stratosphere can be decomposed by reac- tion with nitrogen oxide...
The depletion of ozone (O3) in the stratosphere has been a matter of great concern among...
The depletion of ozone (O3) in the stratosphere has been a matter of great concern among scientists in recent years. It is believed that ozone can react with nitric oxide (NO) that is discharged from the high-altitude jet plane, the SST. The reaction is O3 + NO longrightarrow O2 + NO2 If 0.845 g of O3 reacts with 0.687 g of NO, how many grams of NO2 will be produced? g NO2 Which compound is the limiting reagent? nitric oxide...
Regular flights of supersonic aircraft in the stratosphere are of concern because such aircraft produce nitric...
Regular flights of supersonic aircraft in the stratosphere are of concern because such aircraft produce nitric oxide, NO, as a byproduct in the exhaust of their engines. Nitric oxide reacts with ozone, and it has been suggested that this could contribute to depletion of the ozone layer. NO (g) + O3 (g) ------> NO2 (g) + O2 (g) The reaction is first order with respect to both NO and O3 concentrations and has a rate constant of 2.20 x 107...
Ozone decomposes to molecular oxygen: 2 O3(g) ⇋ 3 O2(g). The following is a proposed mechanism...
Ozone decomposes to molecular oxygen: 2 O3(g) ⇋ 3 O2(g). The
following is a proposed mechanism for the reaction:
Step 1: O3(g) ⇋ O2(g) + O(g) (fast) Step 2: O3(g) + O(g) ⇋ 2
O2(g) (slow)
Provide a valid rate law for the overall ozone decomposition
reaction based on this mechanism.
4. Ozone decomposes to molecular oxygen: 203(g) — 3 O2(g). The following is a proposed mechanism for the reaction: Step 1: 03(g) – O2(g) + O(g) (fast) Step 2:...
Ozone (O3) in the atmosphere can react with nitric oxide (NO): 03(g) + NO(g) --> NO2(g)...
Ozone (O3) in the atmosphere can react with nitric oxide (NO): 03(g) + NO(g) --> NO2(g) + O2(g). (AH° = -199 kJ/mol, 45º = -4.1 J/K·mol) Write answers to three significant figures. a. Calculate the AG°(K9/02.) for this reaction at 25°C. b. Determine the temperature(°C) at which the reaction is at equilibrium.
Ozone (O3) in the atmosphere can react with nitric oxide (NO): O3(g) + NO(g) --> NO2(g) +...
Ozone (O3) in the atmosphere can react with nitric oxide (NO): O3(g) + NO(g) --> NO2(g) + O2(g). ( ΔH° = –199 kJ/mol, ΔS° = –4.1 J/K·mol) Write answers to three significant figures. a. Calculate the ΔG°( kJ/mol) for this reaction at 25°C. b. Determine the temperature(oC) at which the reaction is at equilibrium.
Ozone (O3) in the atmosphere can be converted to oxygen gas by reaction with nitric oxide...
Ozone (O3) in the atmosphere can be converted to oxygen gas by reaction with nitric oxide (NO). Nitrogen dioxide is also produced in the reaction. What is the enthalpy change when 8.50L of ozone at a pressure of 1.00 atm and 25°C reacts with 12.00 L of nitric oxide at the same initial pressure and temperature? [∆H°f (NO) = 90.4 kJ/mol; [∆H°f (NO2) = 33.85 kJ/mol; ∆H°f (O3)= 142.2 kJ/mol] [O3 + NO O2 + NO2] show all work...
Ozone (O3) in the atmosphere can react with nitric oxide (NO): O3(g) + NO(g) --> NO2(g)...
Ozone (O3) in the atmosphere can react with nitric oxide (NO): O3(g) + NO(g) --> NO2(g) + O2(g). ( ΔH° = –199 kJ/mol, ΔS° = –4.1 J/K·mol) Write answers to three significant figures. a. Calculate the ΔG°( kJ/mol) for this reaction at 25°C. Blank 1 b. Determine the temperature(oC) at which the reaction is at equilibrium.
If molecular oxygen is reacting at a rate of 0.024 M/s in the following reaction; 4...
If molecular oxygen is reacting at a rate of 0.024 M/s in the following reaction; 4 NO2(g) + O2(g) → 2 N205(8) at what rate is N2O5 being formed? O 0.048 M/s 0.096 M/S 0.024 M/s 0.012 M/s The rate law for the reaction 2 NO, +O3 -- N2O5 + O, is rate - k[NO][03]. Which one of the following mechanisms is consistent with this rate law? NO2 + NO2-N202 + O2 (slow) N2O2 +O3-N20s (fast) NO2+O3 -NO3 + O2...
2. Consider this two step mechanism for a reaction… Step 1 NO2 + O3 --> NO3 ...
2. Consider this two step mechanism for a reaction… Step 1 NO2 + O3 --> NO3 + O2 slow; rate determining step Step 2 NO3 + NO2 --> N2O5 fast a. What is the overall reaction? b. Identify the intermediates in the mechanism. c. Write the rate law expression for each step of the mechanism including any reversible reactions. c. What is the predicted rate law expression? Be sure to only list reactants from the overall equation and not intermediates...
17) Consider the reaction between nitrogen monoxide and ozone that occurs in the stratosphere. NO(g) +...
17) Consider the reaction between nitrogen monoxide and ozone that occurs in the stratosphere. NO(g) + O3(g) → NO2(g) + O2(8) a. Write the rate law for this elementary step reaction. b. By what factor would the rate of this reaction change if you doubled the concentration of NO? c. The Arrhenius constant, A, is 8.7x102 cm molec's and the activation energy is 63 kJ/mol. What is the rate constant for the reaction at a typical stratosphere temperature (at 35...
Ozone decomposes to molecular oxygen: 2 O3(g) ⇋ 3 O2(g). The
following is a proposed mechanism for the reaction:
Step 1: O3(g) ⇋ O2(g) + O(g) (fast) Step 2: O3(g) + O(g) ⇋ 2
O2(g) (slow)
Provide a valid rate law for the overall ozone decomposition
reaction based on this mechanism.
4. Ozone decomposes to molecular oxygen: 203(g) — 3 O2(g). The following is a proposed mechanism for the reaction: Step 1: 03(g) – O2(g) + O(g) (fast) Step 2:...
Ozone (O3) in the atmosphere can react with nitric oxide (NO): 03(g) + NO(g) --> NO2(g) + O2(g). (AH° = -199 kJ/mol, 45º = -4.1 J/K·mol) Write answers to three significant figures. a. Calculate the AG°(K9/02.) for this reaction at 25°C. b. Determine the temperature(°C) at which the reaction is at equilibrium.
If molecular oxygen is reacting at a rate of 0.024 M/s in the following reaction; 4 NO2(g) + O2(g) → 2 N205(8) at what rate is N2O5 being formed? O 0.048 M/s 0.096 M/S 0.024 M/s 0.012 M/s The rate law for the reaction 2 NO, +O3 -- N2O5 + O, is rate - k[NO][03]. Which one of the following mechanisms is consistent with this rate law? NO2 + NO2-N202 + O2 (slow) N2O2 +O3-N20s (fast) NO2+O3 -NO3 + O2...
17) Consider the reaction between nitrogen monoxide and ozone that occurs in the stratosphere. NO(g) + O3(g) → NO2(g) + O2(8) a. Write the rate law for this elementary step reaction. b. By what factor would the rate of this reaction change if you doubled the concentration of NO? c. The Arrhenius constant, A, is 8.7x102 cm molec's and the activation energy is 63 kJ/mol. What is the rate constant for the reaction at a typical stratosphere temperature (at 35...
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