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15-23 Provide the missing reagents in the reaction sequence shown J. Am. Chem. Soc. 2003, 125, 9554). Note that more than one
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Answer #1

ANSWER: Among the given reactions,

  1. Step-1 is the selctetive reduction of an ester group to alcohol followed by protecting the allylic alcohol with THP group.
  2. Step-2 is the deprotection of allylic alcohol followed by it's oxidation to an aldehyde group.

Below given are the reagnets with the scheme.

Given scheme can be filled as ahown below OTBDPS OTBDPS CHO 1) DIBAL-H, -78°C 2) THP, PPTS 1) TBAF 2)MnO2 EtO2C ΤΗΡΟ THP。 Ind

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