
3. Fill in the reagents or products for the following reactions. Note some boxes will require...
2. REACTIONS AND REAGENTS: Fill in the following boxes with the appropriate reagents or products. Note, most of the reagent problems will have more than one step. Also, for the last three please use aldehyde III (benzaldehyde) as the starting material. оснусн, II CH,CH, OH H NH2 IV H2NCH, cat H+ CH, H-N CH, , NaBH,CN Br2. FeBr 3 Cros, H2SO4 acetone
Determine the missing products or reagents. Draw arrow pushing
mechanisms for 3 of the above reactions.
1) (27 points) Provide the missing reactants, reagents or products 1) NaBH4 2) H30+ H30* H-= - Nat CO2H HON H+ muly & West NH NH2, KOH 1) PP / H 2) H30+ Croz H2SO4 HO H20 1) Mg, EtOEt OH 3) H30+
The scheme below shows the synthesis of an antihypertensitive agent (drug used to treat high blood pressure). Answer the questions that follows. a Br 1 Br CI с CO Me + Meo H2NCO Me (Question 3) B OME CN CN CN CN 6 2 3 4 5 CO Me CO Me Buz SnNz d Final product (9) (1) KOH, heat (2) H+ work up partial hydrolysis (Question 4) CAH, CAH, CN 7 NH NEN 8 Question 1 Select the best...
2. Provide the missing products/reagents for the following reactions (2 pts each, 12 pts) 3. Protecting groups are important in Organic synthesis. We have seen 3 different protecting groups so far. Pick one and show how it is added, how it is removed, and what unwanted reactivity of the starting functional group it avoids. 4 pts) It is actually possible to oxidize ketones to esters using a reaction we have not talked about the Baeyer Villager reaction - which uses...