Question

To determine the equilibrium constant for the reaction 12 +2SCNI(SCN)2 I 25.0 mL of a 0.0100 M aqueous solution of I2 was extracted with 10.0 mL of CHCl3. After extraction, spectrophotometric measurements revealed that the I2 concentration ofthe aqueous layer was 1.12 × 10-4 M. An aqueous solution that was 0.0100 M in I2 and 0.100 M in KSCN was then prepared. After extraction of 25.0 mL of this solution with 10.0 mL of CHCls, the concentration of I2 in the CHCls layer was found from spectrophotometric measurement to be 1.02 x10-3 M. What is the distribution constant for I2 between CHCls and H20? Distribution constant- Submit
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Answer #1

Concentration of I2 in CHCl3 = 0.00102

Concentration of I2 in H2O(aqeous) = 0.000112

Distribution constant = 0.00102/0.000112 = 9.107

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