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Under which assumptions does the activation energy of desorption equal the adsorption energy?

Under which assumptions does the activation energy of desorption equal the adsorption energy?

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Answer #1

This situation happen only at equilibrium. i.e., at Equilibrium both rate of adsorption and rate of desorption are same.

It occurs because activation energy of desorption equal the adsorption energy.

Now assumptions of Langmuir adsorption isotherm.

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