
Given reactioon is
MnO2 + 4 HCl ---> MnCl2 + Cl2 + 2 H2O
Mass of MnO2 = 26 g
Molar mass of MnO2 = 86.94 g/mol
No. of moles of MnO2 = 26 g / 86.94 g/mol = 0.299 moles
Mass of HCl = 30 g
Molar mass of HCl = 36.46 g/mol
No. of moles HCl = 30 g / 36.46 g/mol = 0.823 moles
According to reaction stoichiometry
1 moles of MnO2 require 4 moles of HCl
0.299 moles of MnO2 require 4 * 0.299 moles = 1.196 moles but we have 0.823 moles of HCl only
so HCl is limiting reactant
According to reaction stoichiometry
4 moles of HCl will produce 2 moles of H2O
so 0.823 moles of HCl will produce 0.823 / 2 = 0.4115 moles of H2O
Molar mass of H2O = 18 g/mol
Mass of H2O = No. of moles * Molar mass = 0.4115 moles * 18 g/mol = 7.41 g
Answer is (B) 7.41 g
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