Question

Calculate ДG at 600 K for the following reaction: P4g) + 502(g) ^ P4010(s) where the initial pressures are P,-0.52 atm and P,

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Answer #1

Answer:

Given reaction is

P4(g) + 5O2(g) <-------> P4O10(s)

Kp=1/[P(P4(g))] x [P(O2(g))]^5

Here P4O10(s) is pure solid, therefore it doesn't participate in Kp expression.

Given P(P4(g))=0.52 atm, P(O2(g))=(2.1x10^-3) atm

Kp=1/(0.52) x (2.1x10^-3)^5

Kp=4.7 x 10^13

Since ∆G=- RT lnKp

Where R=8.314 J/mol K, T=temperature = 600 K.

∆G=-(8.314 J/mol.K x 600 K) ln(4.7x10^13)

∆G=-157049.88 J/mol

∆G=157.05 kJ/mol. (Since 1kJ=1000 J).

Please let me know if you have any doubt. Thank you

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