6- Predict the product of the foliowing reactions. Assurme the Assume the necessary work up. (5pts...
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
3. Predict the product(s) using the same alkene reactant for the following reactions: HB H.O, hv H.0/H,0 1, HE, THI | 0 2. NaBH,/NaOH 1. B.H/THF 2. H.O./NaOH KMnO,H,O cold 1. Oso 2. NaHSO, 1. KMnO,/OH/heat 2. H,0 1. O,CH,CI 2. Zn/H,
2. Predict the product(s) using the same alkene reactant for the following reactions: H,O, hv H5OH,O 1, HE. THI -H0 2. NaBH,/NaOH 1. B H/THF 2. H.O./NaOH KMnO /H,0 cold 1. Oso 2. NaHSO 1. KMnO/OH heat 2. H,0 1. O,/CH,CI, 2. Zn/H,0 1.0, 2. H,O/OH
4. Predict the product(s) using th using the same skene reactant for the following reactions 10 CH,CI Br CH,OH HI DBE LIB H.Ohv H.O/H,0 1. Hg. THF-H,O 2. NaBH/NaOH 1. B.H/THF 2. H.OX/NaOH KMnO/H,O cold 1. Os 2. NaHSO, 1. KMnO/OH/heat 2. H,0 1. O,/CH,CI, 2. Zn/H,O
1. Predict the product(s) using the same alkens reactant for the following reactions PUC CH,CI, Bry CH,OH HI DBr HBr H,O,/hv H,OH,O 1. Hg. THF-H,0 2. NaBH,/NaOH 1. B.H/THE 2. H,O,/NaOH KMnO,H,O cold 1. OsO 2. NaHSO, 1. KMnO/OH/heat 2. H0 1. O,/CH,CI, 2. Zn/H,0 1.0, 2. HOOH
5. Indicate the preferred product for the following reactions. Assume proper work-up for each step. (7 points each) a. HNO H2SO OCH, AIC c. Br2, FeBr d. NBS hv KMnO NaOH, Δ 1)へ02
2. Draw the major product for the following reactions.
6.Draw the final product for the following reactions
2. Draw the major product for the following reactions. 1) TCI 2) NaOEL, Heat 3) 0 4) DMS 1) NBS, heat (1 eq.) 2) NaNH, DMS0 3) KMnO4 (aq) NaOH, cold 4) NaCl acetic acid 1) , 2) H.O 3)Ni, 1, 150, 100 atm 1) R RH 2) H.O., NaOH 3) NBS, heat (I eq) 1) KMnO heat 2) Na, NH, CH,OH 3)...
write a major product for each of the following reaction,
indicate appropriate stereochemistry
1.(CH3)3COK, (CH3)2COH 2. Brz, cena 2 3. x's NaNH2 ; H20 W 14. HgSO4, H2SO4, H2O ÇI 1. x's NaNH2; H20 * 2. k, NH3, CH3CH2OK 3. KMnO4 , H2SO4, 4 1. B2H, THF; NaOH(aq), H202 2. SOBrą, o 1. H2SO4, A OH 318 , NaNH2 4. H2, Lindlar catalyst 2. HBr, H202 3.(CH3)3COK, (CH3)3COH 4. R-COOH; H30°
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5pts Q1. Predict the major product of each of the following reactions. Show the stereochemistry of the product when needed. 2.5pts Q2. How would you carry out the following transformation, more than one step may be needed (note: use the specified starting material and any other organic or inorganic compound or reagent) ОН 1) KMnO A) 2) Н,о* он 1)Hg(OAc)2, H20 2.5pts Q2. Propose a mechanism for the...
Predict the major organic product of products of each of the following reactions. a) (CH),CHCH-CH- H2SO4 HO b) (CH3),CHCH=CH, 1. Hg(OAc), H2O 2. NaBH 1. BH3-THF c) (CH3),CHCH=CH2 2. H2O3, NaOH