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Consider 0.05 mol of diatomic Oxygen in a container with initial volume 1 L and initial pressure 1 atm. The Oxygen undergoes

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Answer #1

(1) adiabatic constant \gamma = 1.4

Final volume V2 = (P1/P2)V1\gamma =( (1/3)11.4 )1/1.4= 0.46 L

(2) work done w= (P1V1-P2V2)/(\gamma-1) = (1.01325×105×0.001- 1.01325× 3×105×0.00046)/0.4= -97.96 Joule

(3) change in temperature T1-T2= w(\gamma-1)/nR= (-97.96×0.4)/(0.05×8.314) = -94.27K

(4) cometing the process very fastly in isolated chamber.

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