Question

can you help me finish analzying the MS peaks

Bare Reak- Relative Intensity a elevage 25 50 100 125 150 m/z

Answer 1

Solution - Alcohola , like alkyl holides ond ethers. undergo a cleavage with the largest a substituent being the one most_readily cleaved, consequently, the mass spectrum of 2- hexanol 'shows a base peak at m/z = 45 la-cleavage of a butyl-radical). and small peak al m/2 = 87l a cleavage of_a_methyl radical). CH₂ C4, C4-07- ch-uz ton Cry-cy, _CH₂-U), - at cHz - _mz= 98 _ ton -e cH₃-c4-01, che c3 m/2 = 98 X-cleavage ch₂CH₂CH₂CH2 + CHECHzon 메트도 x-cleavage CH₂ H 2 CH ₂ CH = on tch=CH2 m/2 = 73 __ 73