Answer is:

Yes.
Well we need to perform a chi square test of goodness of fit in order to answer this question:

(1) Null and Alternative Hypotheses
The following null and alternative hypotheses need to be tested:

Ha: Some of the population proportions differ from the values stated in the null hypothesis
This corresponds to a Chi-Square test for Goodness of Fit.
(2) Rejection Region
Based on the information provided, the significance level is α=0.01, the number of degrees of freedom is df=6−1=5, so then the rejection region for this test is R={χ2:χ2>15.086}.
(3) Test Statistics
The Chi-Squared statistic is computed as follows:

(4) Decision about the null hypothesis
Since it is observed that χ2=37.061>χc2=15.086, it is then concluded that the null hypothesis is rejected.
(5) Conclusion
It is concluded that the null hypothesis Ho is rejected. Therefore, there is enough evidence to claim that some of the population proportions differ from those stated in the null hypothesis, at the α=0.01 significance level.
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