Question 10 continues N(CH3)2 HNO2 H2SO4 55°C ON- (0 CF COOH 00H ? CH Cl BOC...
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CH3 H2O + 1. H-C-CH-CH-CH2 CH3 CH C 2, CHy-CH2-CH-CHOHPCC 25°C 50-55°C + HNO H2SO4 он H2CrO4 CH,CHCH acetone, 35°c Et O 2150113H20 5. CH3(CH2)2MgBr+ CH3(CH2)sC(CH2)sCH3 Nall CH2-CHCH2l H2SO4 140°C 6. CH3CH2CH2OH 7. CHCH CHOH 1) LiAIH(O-t-Bu)3,-78°C 2) H20 8. CH,C-CI HBr 9. CH2 CH-CH-CH2 40°C 10. H3C CIH2 Benzene 100℃ H3C 1. LiAIH/Et2O 11. CH,CH2CH,COH 2. H,0 12. + CH,CH,cCI AIC Benzene, 80°C 13. Br2 heat CH3 AlcI 15. 25°C conc. H2SO4 NaBH4...
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C(CH₃), CI - OCH₂CH3 - Br CH₂ CH2 -OCHS, C(CH), Cl H23,22°C CHSCH (CH)CI Ochela O (H3 ③ CH₂ - OH H2SO4 CH₃ H2O 0 CH2CH(CH) CH404 Hour tout ② H-C=C-H 24 25 16H₃ THE 2) H2O2, OH CH3 HgOnc, H2O DH 2-OH, NOBH4 KMnO4 OH, H2O CHEC-CIH - An @ KM, 04, cold 12 C=CH OH, H₂O
Predict the products, if any, of the following reactions. COOH (1) LiAlH (2) H2O* (b) CH B (1) NaCN (2) 40*, heat (1) SOCI2 (a) oct-4-ino KMnO4 H20 (warm , conc.) (2) AICI COOH Ph 10 O Na,Cr,O, H,SO4 BH CH,OHN_C6:0, 14,50. CHCH.–CH-COOH BH, CH,OH (1) CH,CH, -CH-COOH CH,OH KMnO4, H2O (warm, conc.) KMnO,H,O (hot , conc.)
Predict the products.
1. TsCl, pyridine SNa OH NaH HBr 2 eq, 0 °C H2SO4 CH3 heat HBr heat 1. PBr3, Et20 2. NaCN NaH OH HBr 0 °C CH3 H2SO4 heat
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem One. Assume 168 uL A and 123 uL B and one drop of concentrated H2SO4 were allowed...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem Two. Start over. This time assume A is a solid and 423.6 mg of A was measured...
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
H2SO4 Heat нас 2 CH-OH H₂ CH-0 2 H3C-OH + H2C CR A C | CH3 0-CH. нас CH3 dimethyl terephthalate 194.19 g/mol d = 1.075 g/mL bp = 288°C isopropanol 60.10 g/mol 0.7855 g/mL bp = 82.3 °C methanol 32.04 g/mol d = 0.7914 g/mL 64.6 °C diisopropyl terephthalate 250.29 g/mol d = 1.076 g/ml (est.) bp > 300 °C (est.) Problem One. Assume 168 uL A and 123 ul B and one drop of concentrated H2SO4 were allowed...
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T CH2 2. ? CH2 he N(CH3)2 O2N HaC CH3 Phosgene, ? (Review a 3. O-CC2 2 CO2H PY ? HaC 4. Нас OH +CH3 NH2 ? H + excess CH30H ? 6. CH(CH2)16 heat b-(CH2)1CH3 heat ? 7. CaHs-C O-CH2 + NH2-OH hydrorylarnine O-
Practice Set-lll CH3 o 1. H3c-C- CHa a HaC, CH3 PY ? H-C-N H Нас + OH T...
Question 5 (1 point) Saved What arrow correctly identifies a peptide bond? LED H2N -CH-CJN-CH-C-R-CHCN-CH-8 CH-OH - CH₂ CH3 Question 4 (1 point) Identify all the amino acids that can be produced using the three letter designation (Use your textbook). HN-CH-C-N-CH-C-N-CH-C-N-CH-C CH-OH CH, 0 0 Al...Gly...-Cys...-Ser Gly.-.-Ala----Glu ---Met Glu----Ala----Thr----Cys Ala-Gly-Thr-Tyr 0 0 Question 3 (1 point) Use the three letter designation for the amino acids to write the tetrapeptide order: HN-CH-C-N-CH-C-N-CH-C-N-CH-C 525-5 Ala...Gly...Cys-..-Ser Gly....Ala---- Glu---- Met Glu---- Ala...-Thr-Cys OCys...-Ala----Gly-Ser Question...