![PCC EINH2 [H] Ph CI NaBH3CN 1. excess LAH 2. Ho 1 equiv. 2-chloro propane 1.H SOZ/HNO Excess Brz AICI, 2.Fe/HCI 1. NaNO2 /HCI](http://img.homeworklib.com/questions/941cb280-b797-11eb-afea-278515f8c791.png?x-oss-process=image/resize,w_560)
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am stuck on the last two steps -x.s. Br2 and NaNO2
PCC EINH2 [H] Ph...
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number...
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
CH, Bre, light CI 1 Brz, AIBr; A B AICI HNO, c CO, HCI; Cuci, AICI3...
CH, Bre, light CI 1 Brz, AIBr; A B AICI HNO, c CO, HCI; Cuci, AICI3 H2SO4 D CH3 HNO3, H2SO4 H F Br SO; H2SO4 G E CO2 I со, A= B= C= D= E= F= G= H= Which reaction sequence best accomplishes this transformation: NO2 SOZH OCH3 Br OCHZ You a) SO3 H2SO4 Pd(OAC)2 HNO, H2SO4 AICI (HO)2B OCH b) HNO3 H2SO4 SO3 H2SO4 Br2 AICI: Pd(OAc)2, base (HO),B. OCH3 c) Zn(Hg) HCI, H20 HNO3 H2SO4 SO, H2SO4...
Don't understand how you get these particular ones. RCO3H y 60,4 ignore stereochemistry NH PCC/CH2Cl2 H...
Don't understand how you get these particular ones.
RCO3H y 60,4 ignore stereochemistry NH PCC/CH2Cl2 H pH = 4 1) Mg/Et20 2) HH HOOH H30+ 3) H20+ ignore stereochemistry 1) 03 Она -- 2) Н,0 Конноллон но* Осоон зууны, COOH 1) Br2, PBrz 2) Н,0 но - ден. 1) H,Crод он —2) А „Соонд HOOC 1) V PPh3 2) Os04 3) NaHSO3 4) I /HCI 1) NaOH 2) PCC(excess)/CH2Cl2 3) pH = 4 MNH NH2 h Br 1) Mg/Et,o 2)...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List...
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
H,Cro SOCI: H,0 Pyridine PCC CH,CI, HIO HR Peroxide 2. H,0,HCI NES CH- - HN CH,I,...
H,Cro SOCI: H,0 Pyridine PCC CH,CI, HIO HR Peroxide 2. H,0,HCI NES CH- - HN CH,I, Zn(Cu) ether 1.0, 2. (CH) KCN HCN 1.00 2. NaHSO, H,0 HO 2. HCI, H20 H.SO 1. BH. THE 2. H,O, NaOH 1. HgOAC), 2,0 2. NaBH, HUNCH, 1. NBH 2. H.O
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH...
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
If someone could help with these two reactions I would appreciate it. d. 1. NBS, h...
If someone could help with these two reactions I would
appreciate it.
d. 1. NBS, h 2. KOt-Bu, Δ 3. m-CPBA 4. CH3MgBr 5. H3o 6. Na Cr207, Ho 7. excess Br2, excess NaOH e. 1. PCla 2. он Li 3. HO 1 equiv BuOH
how do you solve these? I am stuck. DUE AFTER COMPLETING LAB. ANSWER IN SPACE PROVIDED...
how do you solve these? I am stuck.
DUE AFTER COMPLETING LAB. ANSWER IN SPACE PROVIDED Determine the K, of the weak acid HX knowing that a 0.10 M solution of LiX has plH of 8.90. 1. Pyridine, C.H,N, is a weak base and reacts with HCI as folleows 2. C.H,N (aq)+ HCI (aq) CH,NH (aq) CI (aq) What is the pH of a 0.015 M solution of the pyridinium ion (CSH5NH+)? The K, for pyridine is 1.6 x 10-9....
Propose an efficient synthesis for the transformation below,
using two sequential reductive aminations. Enter
the appropriate number or letter from the reagent list handout.
Propose an efficient synthesis for the transformation below, using two sequential reductive aminations. Enter the appropriate number or letter from the reagent list handout. Step 1 + NaBH3CN, H+, Step 2 - NaBH3CN, H+ Reagent List (Updated 4/30/2020) Enter # or letter in the appropriate boxes. Note: Exam responses are case insensitive Alkyl Halides (X = Cl,...
Propose an efficient synthesis for the transformation below. Enter the appropriate number of letter from the reagent list handout Step 1 Step 2 Step 3 OH Alkyl Halides (X = CI, Br or 1) and Acyl chlorides: Assume Allig 15 present, if needed CIP CU CH3X X CI E A B EE Ketones. Aldehydes and Epoxides: Assume "then H20" is included if a protonation step is needed F A A K 0 MN Р Grignard, Wittig and Organocuprate Reagents: Assume...
CH, Bre, light CI 1 Brz, AIBr; A B AICI HNO, c CO, HCI; Cuci, AICI3 H2SO4 D CH3 HNO3, H2SO4 H F Br SO; H2SO4 G E CO2 I со, A= B= C= D= E= F= G= H= Which reaction sequence best accomplishes this transformation: NO2 SOZH OCH3 Br OCHZ You a) SO3 H2SO4 Pd(OAC)2 HNO, H2SO4 AICI (HO)2B OCH b) HNO3 H2SO4 SO3 H2SO4 Br2 AICI: Pd(OAc)2, base (HO),B. OCH3 c) Zn(Hg) HCI, H20 HNO3 H2SO4 SO, H2SO4...
Don't understand how you get these particular ones.
RCO3H y 60,4 ignore stereochemistry NH PCC/CH2Cl2 H pH = 4 1) Mg/Et20 2) HH HOOH H30+ 3) H20+ ignore stereochemistry 1) 03 Она -- 2) Н,0 Конноллон но* Осоон зууны, COOH 1) Br2, PBrz 2) Н,0 но - ден. 1) H,Crод он —2) А „Соонд HOOC 1) V PPh3 2) Os04 3) NaHSO3 4) I /HCI 1) NaOH 2) PCC(excess)/CH2Cl2 3) pH = 4 MNH NH2 h Br 1) Mg/Et,o 2)...
Ph cyclopropene HF CH h) OH 1. POCICH.Ch 2. Pri 3 NH4Cl ag) 1.) 1. Li/THE 2.CO 3.NH.CH HNO k.) NH 1. HNO (aq) 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCU. n) -OH XS H.CO acetone он 0.) OH XS Bobbit's SiO, CH.CH -OH 1. Ch. AICI 2 NaOH, 30 C 4,000 psi 3. HCI 9.) SCH 2Na, ETOH, NH, r.) 1. LIETO 2. oxirane 3. H,00 1.2 PY-MOBI OMe 2. NHCl(aq) t.) 1. Cl/ Feer...
17. Use ANY needed reagents to effect the following transformation. (30 points) starting material product List of Reagents -N:C:N- KMnO4, H2SO4 8 00 (CH3),COCOCOC(CH3)3 Ag(NH3)2+, 120 Fe, HCI KMnO4, NaOH, H2O, cold AlCl3 Bra (excess), NaOH (excess), H20 Brz, Fe Br2, H20 Br2, H2O, H3O+ Br2, hy Br2, NaOH (excess), H2O Br2, P Buli CF3CO,H CH;=0 Formaldehyde оо CH3COCCH o CH_CC1, pyridine H2, Lindlar's catalyst H2.Pd/C H2, Pa/C, high pressure H, Raney-Ni HANNH HENNH, KOH, (HOCH2CH2)20, heat H2O H20, H2SO4,...
H,Cro SOCI: H,0 Pyridine PCC CH,CI, HIO HR Peroxide 2. H,0,HCI NES CH- - HN CH,I, Zn(Cu) ether 1.0, 2. (CH) KCN HCN 1.00 2. NaHSO, H,0 HO 2. HCI, H20 H.SO 1. BH. THE 2. H,O, NaOH 1. HgOAC), 2,0 2. NaBH, HUNCH, 1. NBH 2. H.O
a.) H H_Cro acetone b.) 1. XS KMnO,/KOH/HOIA 2.H30* c.) ni XS NaBH,, H,0 H OH d.) o 1. XS LAIH/THF/-78 °C 2. H20 H OH e.) NaNH / lig NH3 f.) Br 1. Mg/THE 2. CO2 3. H30 9.) Ph Ph cyclopropene HF CH h.) OH 1. PCCICH.CH 2. Pri 3. N,Cag) 1. LITHF 2.CO 3. NH.Ca) HNO, NH 1. HNO () 2. NaSCH CH.CH AICI, 3-chloro-2-methylpentane m.) 1.Pr.CI. AICI 2. NBS, CCH n.) OH XS H.COM acetone OH...
If someone could help with these two reactions I would
appreciate it.
d. 1. NBS, h 2. KOt-Bu, Δ 3. m-CPBA 4. CH3MgBr 5. H3o 6. Na Cr207, Ho 7. excess Br2, excess NaOH e. 1. PCla 2. он Li 3. HO 1 equiv BuOH
how do you solve these? I am stuck.
DUE AFTER COMPLETING LAB. ANSWER IN SPACE PROVIDED Determine the K, of the weak acid HX knowing that a 0.10 M solution of LiX has plH of 8.90. 1. Pyridine, C.H,N, is a weak base and reacts with HCI as folleows 2. C.H,N (aq)+ HCI (aq) CH,NH (aq) CI (aq) What is the pH of a 0.015 M solution of the pyridinium ion (CSH5NH+)? The K, for pyridine is 1.6 x 10-9....
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