The use of the name “metallocenes” to describe complexes with the general formula (C5H5)2M is derived from the word “ferrocene”, which in turn was given to the iron containing compound (C5H5)2Fe because its cyclopentadienyl rings exhibited aromatic behavior typical of benzene. Given its name, what type of reactivity (or lack thereof) would be expected for ferrocene?
Similar to benzene it is also aromatic due to the presence of 10
1 electrons (Huckle's rule,each cyclopenttadienyl Ring contributes
5 electrons
).
Similar to benzene it undergo Aromatic Electrophilic Substitution
reactions.
The use of the name “metallocenes” to describe complexes with the general formula (C5H5)2M is derived...