Question

DATA TABLE Buffer A Buffer B Mass of NaC2H3O2 used to prepare buffer (g) 0.149 g...

DATA TABLE

Buffer A

Buffer B

Mass of NaC2H3O2 used to prepare buffer (g)

0.149 g

1.49 g

Volume of buffer prepared (mL)

100.0

100.0

Molar concentration of HC2H3O2 in buffer (M)

0.1

1.0

Initial pH of buffer

4.24

4.33

Volume of 0.5 M NaOH to raise pH by 2 units (mL)

1.5

19.0

Volume of 0.5 M HCl to lower pH by 2 units (mL)

1.0

5.0

Volume of 0.5 M NaOH at equivalence point (mL)

1.75

19.75

3.   Say, for example, that you had prepared a Buffer C, in which you mixed 8.203 g of sodium acetate, NaC2H3O2, with 100.0 mL of 1.0 M acetic acid.

a. What would be the initial pH of Buffer C?

b. If you add 5.0 mL of 0.5 M NaOH solution to 20.0 mL each of Buffer B and Buffer C, which buffer’s pH would change less? Explain.

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