Question

please analyze two spectrums and discuss briefly why you think so etc.

  1. Assign all the resonances and describe how they can be used to assess complete transformation of the starting material to product.
  2. The Infrared data for the starting material and the product appear below. Assign the major absorptions and describe how they can be used to assess complete transformation of the starting material to product.
  3. The mechanism provided below describes the oxidation of cyclohexanol. Adapt it to the oxidation of 2-octanol. 2-Octanol may be written as

THE SYNTHESIS OF 2-OCTANONE FROM THE BLEACH OXIDATION OF 2-OCTANOL OL mocion me can NaoCl(aq) CH3CO2H (1)Mechanism of the oxidation with bleach: Na-OCI +H30® = Na + | H-O-ci + H2O Но + HS H30 LOH Nato 0-0 Photo deteng - H HĐ + I ,

LAB - THE SYNTHESIS OF 2-OCTANONE FROM THE BLEACH OXIDATION OF 2-OCTANOL

ܗܗܗ ܗ Fredictec SH NU RELESS ܘ ܗ eest ܙܕܘܠ ܗ ܗ ܩ ܘܕ \\\ ܕܬܐ ܪܗܘܘ osܘ 0055 0050 645܂0 0040 01635 DEOD ܪܐܘܘ -070 -4015 ܘܠܐܘ ܪܘPredicted IH NMR Spectrum -3.38 -0.10 -0.09 -0.08 -0,07 -0.06 -0.01 -0.00 -0.01

INFRA-RED SPECTRUM OF 2-OCTANOL Infrared Spectrum Transmitance 3500 3000 1500 1000 500 2500 2000 Wavenumbers (cm-1)

INFRA-RED SPECTRUM OF 2-OCTANONE S DBS-NO-3299 IR-NIDA-01497 : LIQUID FILM HIT-NO-2234 TSCORE 2-DCTANONE CH10 TRANSMETTANCE 2

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Answer #1

- 27th w July 13 th Wk.. Days : 185-180 Thursday Naoul lan Utco, H 0 Naoe & thot watt Hourlho Tho - ci + izot d, 1.1ppm. t,

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