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1) a student obtained a boiling point of 82.5 C during the simple distillation of an...

1) a student obtained a boiling point of 82.5 C during the simple distillation of an unknown alcohol. However, when a solution of same alcohol and water was distilled, the boiling point obtained was 80 C, give all possible reasons.

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Answer #1

This is because of Positive deviation from Raoult's law.

Initially, when only alcohol (say A) was present there were only A-A interactions. Thus, it boils at normal boiling point.

While, on adding water (say B) there exists A-B interactions as well .since, A-B interactions are weaker than A-A interactions, hence, alcohol prefer to go into vapour state. thereby, increasing the vapour pressure and decreasing the boiling point.

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