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GlauUUUUR URION Downloadable eTextbook signment FULL SCREEN PRI ES Chapter 17, Question 27 Parameterization Calculate Eº for

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Answer #1

E0cell= E0red-E0oxd

Oxidation (Anode) : P                          H3PO4        -0.411

Reduction (Cathode) : NO3-                           NO      +0.957

3 P + 5 HNO3 + 2 H2O                            5 NO + 3 H3PO4

3 P(0)   - 15 e-                           3 P (V)               Oxidation

5 N(V) +15 e-                                      5 N(II)                       Reduction

E0cell= E0red-E0oxd = 5 x0.957 – 3(-0.411) = 4.785 + 1.233 = 6.018 V

Answer is 6.02 V

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