
The gas phase decomposition of phosphine at 120 °C PH3(g) 1/4 P_(g) + 3/2 H2(e) is...
The gas phase decomposition of phosphine at 120 °C PH3(g)1/4 P4(g) + 3/2 H2(g) is first order in PH3 with a rate constant of 1.80×10-2 s-1. If the initial concentration of PH3 is 5.86×10-2 M, the concentration of PH3 will be 1.43×10-2 M after s have passed.
The following data are for the gas phase decomposition of phosphine at 120 °C. PH3(g) 1/4 P4(g) + 3/2 H2(g) [ PH3 ], M 4.94×10-2 2.47×10-2 1.24×10-2 6.20×10-3 time, s 0 25.8 51.6 77.4 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is__ s . (2) Based on these data, the rate constant for this order reaction is__ s -1
For the gas phase decomposition of phosphine at 120 °C 4 PH3(g)P4(g) + 6 H2(g) the average rate of disappearance of PH3 over the time period from t = 0 s to t = 27 s is found to be 2.63×10-4 M s-1. The average rate of formation of H2 over the same time period is________ M s-1.
1A. The decomposition of dinitrogen pentoxide in carbon
tetrachloride solution at 30 °C N2O5 2 NO2 + ½ O2 is first order in
N2O5 with a rate constant of 4.10×10-3 min-1. If the initial
concentration of N2O5 is 0.510 M, the concentration of N2O5 will be
M after 402 min h
1B. The gas phase decomposition of phosphine at 120 °C
PH3(g)1/4
P4(g) + 3/2 H2(g)
is first order in PH3
with a rate constant of 1.80×10-2
s-1.
If the...
1. a. The gas phase decomposition of sulfuryl chloride at 600 K SO2Cl2(g) -------> SO2(g) + Cl2(g) is first order in SO2Cl2 with a rate constant of 2.80×10-3 min-1. If the initial concentration of SO2Cl2 is 5.84×10-3 M, the concentration of SO2Cl2 will be _____M after 618 min have passed. b. The gas phase decomposition of dimethyl ether at 500 °C CH3OCH3(g)-------->CH4(g) + H2(g) + CO(g) is first order in CH3OCH3 with a rate constant of 4.00×10-4 s-1. If the...
The gas phase decomposition of hydrogen iodide at 700 K
HI(g)½
H2(g) + ½ I2(g)
is second order in HI with a
rate constant of 1.20×10-3
M-1 s-1.
If the initial concentration of HI is
2.22 M, the concentration of HI
will be _____________________M after
2.21×103 seconds have
passed.
The decomposition of phosphine, PH3, follows first-order kinetics: 4 PH3(g) → P4(g) + 6 H2(g) Calculate the activation energy, Eq, in kJ/mol for the reaction, given that the rate constant k (at 25 °C) = 0.00852 s 1 and k (at 50 °C) = 0.756 s 1. 231 kJ/mol 144 kJ/mol O 56.5 kJ/mol О 99.3 kJ/mol O 111 kJ/mol
The gas phase decomposition of hydrogen iodide at 700 K HI(g)%H2(g) + 12() is second order in HI with a rate constant of 1.20x10-'M',' If the initial concentration of HI is 1.48 M, the concentration of HI will be M after 1.34x10 seconds have passed.
The gas phase decomposition of dinitrogen pentoxide at 335 K N2O5(g) 2 NO2(g) + ½ O2(g) is first order in N2O5 with a rate constant of 4.70×10-3 s-1. If the initial concentration of N2O5 is 4.50×10-2 M, the concentration of N2O5 will be ______ M after 259 s have passed.
The gas phase decomposition of nitrogen dioxide at 383 °C NO2(g)NO(g) + ½ O2(g) is second order in NO2. In one experiment, when the initial concentration of NO2 was 0.449 M, the concentration of NO2 dropped to 5.84×10-2 M after 20.6 seconds had passed. Based on these data, the rate constant for the reaction is_______ M-1 s-1?