Ans. (1) 39.9 ml sodium hydroxide
Explanation:
The balanced chemical reaction between sodium hydroxide and perchloric acid is :
NaOH + HClO4 --------> NaClO4 + H2O
Molarity of sodium hydroxide , M1 = 0.150M
Volume of sodium hydroxide used, V1 = ?
Molarity of perchloric acid, M2 = 0.224M
Volume of perchloric acid used, V2=26.7 ml
Using,
M1V1= M2V2
V1 = M2V2 / M1
V1 = ( 0.224 M × 26.7 ml) / 0.150 M
= 39.87 ml = 39.9 ml
So, volume of NaOH used = 39.9 ml
2) 16.9 ml Hydrochloric acid
The reaction between Hydrochloric acid and sodium hydroxide is :
NaOH + HCl ----------> NaCl + H2 O
Molarity of Hydrochloric acid, M1 = 0.257 M
Volume of Hydrochloric acid, V1= ?
Molarity of sodium hydroxide, M2= 0.150M
Volume of sodium hydroxide, V2 = 29ml
Using,
M1V1 = M2V2
V1 = M2V2/ M1
=( 0.150M × 29.0 ml) / 0.257 M
= 16.9 ml
Thus, volume of HCl used = 16.9 ml
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