Question

[08 pts.] Briefly explain the roles of sodium hypochlorite and acetic acid in the oxidation of cyclohexanol. sodium hypochlorite and acetic aut are added together to create the hypochlurous act, which used to protorate the oth grap on cyclo hexarod. [12 pts.] Draw the major product for each of the following oxidation reactions. кон Na CrO; H2SO4, H,0 Na Cr2O7 H2SO4, H20 CHO PCC

Answer 1

Answer:

Na2Cr2O7, H2SO4, H2O , Are called Jones reagents, and these are used for oxidation of primary and secondary alcohols, primary alcohol are converted into aldehyde (as in reaction a)

And , secondary alcohols are oxidized to ketones (as in reaction 2.)

PCC is also a reagents which is used in catalytic amount for oxidation of alcohols to corresponding carbonyl compunds.

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OH Naz Cr207 T H₂SO4 , HO lo alcohol aldehyde OM Nag Cry Of H₂SO4 H₂O 20 alcohol Ketone PCC Aldehyde t'alcohol