The required concepts to solve the problem are magnetic field, magnetic force and velocity of a charged particle in a magnetic field.
First, using the relation between magnetic field, magnetic force, charge of the particle, velocity of the particle and the angle between the velocity and the field, find the smallest angle between the velocity and the field. Then, using the relation between magnetic field, magnetic force, the charge of the particle, the velocity of the particle and the angle between the velocity and the field, find the largest angle between the velocity and the field.
When a charged particle enters a magnetic field at an angle, it experiences a magnetic force. The relation between magnetic field, magnetic force, the charge of the particle, the velocity of the particle and the angle between the velocity and the field is,

Here,
is the charge of the particle,
is the magnetic force,
is the magnetic field,
is the velocity and
is the angle between the velocity and the field.
(a)
The equation for magnetic force is,

Substitute
for
,
for
,
for
and
for
to find
.

The smallest angle between the velocity and the field is,

(b)
The equation for magnetic force is,

Substitute
for
,
for
,
for
and
for
to find
.

The largest angle between the velocity and the field is,

Thus, the smallest angle between the velocity and the field is
.
Thus, the largest angle between the velocity and the field is
.
A proton moving at 4.50 106 m/s through a magnetic field of magnitude 1.80 T experiences...
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