Sample of solid aluminum (Al) and solid magnesium (Mg) are placed in a solution containing 1.0 M Al3+ ion and 1.0 M Mg2+ ions at 25 o C. For the mixture…
(1) write the BALANCED spontaneous reaction,
(2) determine the cell potential (Ecell) in volts,
(3) the free energy (ΔG) in kJ, and
(4) the equilibrium constant (Keq).
Al3+ (aq) + 3 e– "Al (s) Eo = –1.66 V
Mg2+ (aq) + 2 e– "Mg (s) Eo = –2.37 V
Sample of solid aluminum (Al) and solid magnesium (Mg) are placed in a solution containing 1.0...
Use the provided reduction potentials to calculate the equilibrium constant (K) for the following balanced redox reaction at 25 °C: 2Al(s) + 3Mg2+(aq) → 2Al3+(aq) + 3Mg(s) E°(Al3+/Al) = -1.66 V and E°(Mg2+/Mg) = -2.37 V 1.0 × 1024 9.7 × 10-73 1.1 × 1072 4.6 × 1031 8.9 × 10-70
When solid magnesium is reacted with an aluminum phosphate solution, metallic aluminum is produced by single displacement (equation. a): (a) AlPO4(aq)+Mg(s)→Al(s)+Mg3(PO4)2(aq) Balance equation (a) and answer the following: How many grams of aluminum metal should be theoretically produced from 2.338 g of pure magnesium metal. Suposse magnesium metal is the limiting reactant. Molar masses (g/mol): AlPO4 = 121.95 Mg = 24.305 Al = 26.98 Mg3(PO4)2 = 262.86 Important note: Use 3 digits after the decimal place in your answer.
4. A voltaic cell employs the following redox reaction: 2 Fe3+(aq) + 3 Mg(s) → 2 Fe(s) + 3 Mg2+(aq) What is the number of electrons that have been transferred in this redox reaction? 5. Use the following reduction potentials to determine if the reaction in Question 4 represents a voltaic or electrolytic cell and if the reaction is spontaneous or non-spontaneous. Fe3+(aq) + 3 e−(aq) → Fe(s) Eo = −0.036 V Mg2+(aq) + 2 e−(aq) → Mg(s) Eo =...
Model I: The Dissolution of Magnesium Hydroxide in Water When solid Mg(OH)2 dissolves in water, the chemical reaction is: Mg(OH)2(s) Mg2+(aq) + 2OH-(aq) (1) Table I. These are the results after equilibrium has been established for the addition of solid Mg(OH)2(s) to water yielding a final volume of 10.0 L of solution. Total amount of Mg(OH)2 added Mg2+ concentration in the resulting solution at eq OH- concentration in the resulting solution at eq Mass of Mg(OH)2 that does not dissolve...
Magnesium ions and sulfate ions have the following reduction and oxidation reactions and potentials: Mg2+(aq) + 2e– →Mg(s) Eo = –1.18 V 2SO42–(aq)→S2O82–(aq) + 2e– Eo = –2.05 V Why did neither of these half-reactions occur when the magnesium sulfate solution was electrolyzed?
Calculate the theoretical cell potential (E°) of a galvanic cell
under standard conditions made up of copper and magnesium (see Part
II and Table 1 for more information).
PARTIL Creating and Testing Voltaic Cells Introduction and Background for the Voltaic Cells A galvanic cell (sometimes more appropriately called a voltaic cell) consists of two half-cells joined by a salt bridge that allow ions to pass between the two sides in order to maintain electroneutrality. Each half-cell contains the Components of...
20. A galvanic (voltaic) cell is constructed froma half-cell containing a solid aluminum electrode dipped in a 1.0 M Al(NO3)3 solution and a half-cell containing a solid indium electrode in contact with a 1.0 M In(NO3)3 solution. The half-cells are linked by an external circuit (a wire) and by a KCl salt bridge. The cell generates a standard voltage of 1.32 V and the indium electrode is positive. The standard half-cell reduction potential for aluminum, E°(Al3*/Al), is listed in the...
8. (2 pts) Use the tabulated half-cell potentials to calculate AGⓇ for the following balanced redox reaction. 3 Mg2+(aq) + 2 Al(s) 3 Mgs) + 2 A13+(aq) E° Mg2(aq) + 2e → Mg(s) R -2.37 V AP (aq) + 3e + Al(s) O -1.66 V Cathode Anode a. - 2.3 x 10² kJ b. +4.1 x 102 kJ c. +1.4 x 10² kJ d. - 7.8 x 10 kJ
Given: 3Mg(s) +2 A13+(aq) – 2 Al(s) + 3Mg2+(aq) Which of the foloowing statements is/are correct? a. Mg metal is oxidized and Aluminum ion is reduced b. Mg metal is reduced and Aluminum ion is oxidized C. Aluminum metal is oxidized and Magnesium metal is reduced d. Aluminum metal is reduced and Magnesium ion is oxidized e. None of the these is correct Use the standard half-cell potentials listed below to calculate the standard cell potential and standard free energy...
The active ingredients in a particular antacid tablet are aluminum hydroxide Al(OH)3, magnesium hydroxide Mg(OH)2 and an inert "binder". A 500 mg sample of the active ingredients was dissolved in 50.0mL of 0.500 M HCl. The resulting solution, which was still acidic required 30.9 mL of 0.255M NaOH for neutralization. (a) Calculate the number of OH ion moles in the antacid tablet. (b) If the antacid tablet contains 5.0% (mass) of the inert "binder" , how many milligrams of aluminum...