1.
K = 3.70 * 10-4
E0cell = ( 0.05916 / n ) * LogK
E0cell = ( 0.05916 / 2 ) * Log(3.70*10-4)
E0cell = - 0.102 V
2.
deltaG = deltaH - T deltaS = - 583 - 298.15 ( - 0.257 ) = - 506.4 kJ
3.
E0cell = E0Cu2+/Cu - E0Ni2+/Ni = 0.34 - ( - 0.23 ) = 0.57 V
(0.05916 / n )*logK = E0cell
LogK = 0.57 * 2 / 0.05916
K = 1.86 * 1019
4.
Q = [Co2+]2[Cl2] / [Co3+]2[Cl-]2
Q = ( 0.4142 * 0300 ) / ( 0.2102 * 0.8562 )
Q = 1591.2
Nernst equation,
Ecell = E0cell - ( 0.05916 / n ) * log(Q)
Ecell = 0.483 - ( 0.05916 / 2 ) * log(1591.2)
Ecell = 0.388 V
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Express your answer to three significant figures and include the
appropriate units.
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