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Like glucose, fructose can undergo a cyclization reaction. The most common reaction involves the ketone group...

Like glucose, fructose can undergo a cyclization reaction. The most common reaction involves the ketone group and the C5 hydroxyl group. Draw the structures of the two possible reaction products. What is the size of the ring?

Repeat the exercise described in part (a), but use the C6 hydroxyl group instead. What is the size of the resulting ring?

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Answer #1

The reaction of ketone group and the C5 hydroxyl group cyclizes to fructofuranose forms. While, reaction of ketone group and the C6 hydroxyl group cyclizes to fructopyranose forms. See below images.

Image result for fructose ring structure

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