Question

A voltaic cell is based on two lead half cells: Pb+2(aq) + 2 e- → Pb(s)...

A voltaic cell is based on two lead half cells: Pb+2(aq) + 2 e- → Pb(s) Eo = -0.13 v

One half-cell has [Pb(NO3)2] = 0.25 M and one half-cell has [Pb(NO3)2] = 0.0020 M

What is the initial potential produced by the voltaic cell. Express your answer in units of volts with 2 significant digits, but do not include the units on the submitted answer.

0 0
Add a comment Improve this question Transcribed image text
Answer #1

anode : Pb----------------------- > Pb+2 (0.020 M) + 2e-

cathode : Pb+2 (0.25M) + 2e- --------------------> Pb

--------------------------------------------------------------------------------------------------------------------------------

overall : Pb+2 (0.25M) -------------------> Pb+2 (0.020 M)

-------------------------------------------------------------------------------------------------------------------------------------

Ecell   = 0.05916 / 2 * log [0.25 / 0.020]

Ecell = 0.032 V

answer : initial potential = 0.032 V

Add a comment
Know the answer?
Add Answer to:
A voltaic cell is based on two lead half cells: Pb+2(aq) + 2 e- → Pb(s)...
Your Answer:

Post as a guest

Your Name:

What's your source?

Earn Coins

Coins can be redeemed for fabulous gifts.

Not the answer you're looking for? Ask your own homework help question. Our experts will answer your question WITHIN MINUTES for Free.
Similar Homework Help Questions
  • Consider a voltaic cell based on the half-cells: Ag+ (aq) + e - Ag(s) E* =...

    Consider a voltaic cell based on the half-cells: Ag+ (aq) + e - Ag(s) E* = +0.80 V Pb2+(aq) + 2 e-Pb(s) E* = -0.13 V Identify the anode and give the cell voltage under standard conditions: = 0.67 V Ag: E cell B. Pb: E cell = 0.67 V OC. Pb: E cell = 0.93 V D. Pb: E cell = -0.67 V E. Ag: E cell = 0.93 V

  • Design a voltaic cell with the following two reduction half-reactions: Ag+(aq) + e−  ⟶ Ag(s) Eo =...

    Design a voltaic cell with the following two reduction half-reactions: Ag+(aq) + e−  ⟶ Ag(s) Eo = 0.80 V Pb2+(aq) + 2 e− ⟶ Pb(s) Eo = −0.13 V Calculate Eocell and the equilibrium constant K for the voltaic cell at 298 K. Click here for a copy of Final Exam cover sheet.

  • A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Pb2+(aq) + 2e- →...

    A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Pb2+(aq) + 2e- → Pb(s)    Eo = -0.13V Mn2+(aq) + 2e- →Mn(s)    Eo = -1.18V What is the cathode in this voltaic cell? Question options: a. Mn2+(aq) b. Pb(s) c. Pb2+(aq) d. Mn(s)

  • A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Pb2+(aq) + 2e- →...

    A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Pb2+(aq) + 2e- → Pb(s)    Eo = -0.13V Mn2+(aq) + 2e- →Mn(s)    Eo = -1.18V What is the anode half-reaction for this voltaic cell? Question options: a. Mn2+(aq) + 2e- →Mn(s) b. Pb(s) → Pb2+(aq) + 2e- c. Pb2+(aq) + 2e- → Pb(s) d. Mn(s) →Mn2+(aq) + 2e-

  • A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Pb2+(aq) + 2e- →...

    A voltaic cell consists of an Mn/Mn2+ half-cell and a Pb/Pb2+ half-cell. Pb2+(aq) + 2e- → Pb(s)    Eo = -0.13V Mn2+(aq) + 2e- →Mn(s)    Eo = -1.18V What is the cell voltage of this voltaic cell? Question options: a. -1.31V b. +1.67V c. +1.05V

  • An electrochemical cell is based on these two half-reactions: Ox: Pb(s) Pb?" (aq, 0.21 mol L...

    An electrochemical cell is based on these two half-reactions: Ox: Pb(s) Pb?" (aq, 0.21 mol L ')+2 e Erode = -0.13 (V) Red: Mno. (aq, 1.40 mol L-)+4 H+ (aq, 1.5 mol L-') +3 e MnO2 (s) + 2 H2O (1) Ecathode = 1.68 (V) Part A Compute the cell potential at 25°C. Express your answer to two decimal places and include the appropriate units. Ecell = Value Units Submit Request Answer

  • A voltaic cell contains two half-cells. One half-cell contains a zinc electrode immersed in a 1.00...

    A voltaic cell contains two half-cells. One half-cell contains a zinc electrode immersed in a 1.00 M Zn(NO3)2 solution. The second half-cell contains a titanium electrode immersed in a 1.00 M Ti(NO3)3 solution. Zn2+(aq) + 2 e− → Zn(s)     E⁰red  = −0.762 V Ti3+(aq) + 3 e− → Ti(s)     E⁰red  = −1.370 V (a) Using the standard reduction potentials given above, predict the standard cell potential of the voltaic cell. _____ V (b) Write the overall balanced equation for the...

  • A voltaic cell consists of a Pb/Pb2+ half-cell and a Cu/Cu2+ half-cell at 25 ∘C. The...

    A voltaic cell consists of a Pb/Pb2+ half-cell and a Cu/Cu2+ half-cell at 25 ∘C. The initial concentrations of Pb2+ and Cu2+ are 5.30×10−2 M and 1.70 M, respectively. Part A- What is the initial cell potential? Express your answer using two significant figures. Part B- What is the cell potential when the concentration of Cu2+ has fallen to 0.230 M ? Express your answer using two significant figures. Part C- What are the concentrations of Pb2+ and Cu2+ when...

  • A voltaic cell contains two half-cells. One half-cell contains a titanium electrode immersed in a 1.00...

    A voltaic cell contains two half-cells. One half-cell contains a titanium electrode immersed in a 1.00 M Ti(NO3)3 solution. The second half-cell contains a nickel electrode immersed in a 1.00 M Ni(NO3)2 solution. Ti3+(aq) + 3 e− → Ti(s)     E⁰red  = −1.370 V Ni2+(aq) + 2 e− → Ni(s)     E⁰red  = −0.257 V Write the overall balanced equation for the voltaic cell. (Include states-of-matter under the given conditions in your answer.)

  • A voltaic cell contains two half-cells. One half-cell contains a gold electrode immersed in a 1.00 M Au(NO3)3 solution....

    A voltaic cell contains two half-cells. One half-cell contains a gold electrode immersed in a 1.00 M Au(NO3)3 solution. The second half-cell contains a magnesium electrode immersed in a 1.00 M Mg(NO3)2 solution. Au ** (aq) + 3 e Au(s) Ered = +1.498 V Mg2+ (aq) + 2 + Mg(s) Ered = -2.372 V (a) Using the standard reduction potentials given above, predict the standard cell potential of the voltaic cell. (b) Write the overall balanced equation for the voltaic...

ADVERTISEMENT
Free Homework Help App
Download From Google Play
Scan Your Homework
to Get Instant Free Answers
Need Online Homework Help?
Ask a Question
Get Answers For Free
Most questions answered within 3 hours.
ADVERTISEMENT
ADVERTISEMENT