Calculate the pH of a solution containing 0.1 mol of phosphoric acid per liter of solution at SATP knowing that the SATP values of pK1, pK2, and pK3 for H3PO4 are 2.1, 7.2, and 12.4, respectively.
Show your work.
![K for HyPO,-101 -2.1 =7.9×10-3 I 0.1 x2-7.9*10-3 (0.1-x)=0 By solving above equati on we get x 0.0244 M Hox 0.0244M pHlogHo]](http://img.homeworklib.com/questions/5c21ad10-f9eb-11eb-8c20-69a995d4c19c.png?x-oss-process=image/resize,w_560)
Calculate the pH of a solution containing 0.1 mol of phosphoric acid per liter of solution...
Phosphoric acid is a polyprotic acid (more than one proton that gets ionized) with 3 pK values: pK1=2.15, pK2=6.82 and pK3=12.38. Which molecular species are present at pH 6.82? mostly H3PO4 [H3PO4]=[H2PO4-] mostly [H2PO4-] [H2PO4-]=[HPO42-] mostly [HPO42-] [HPO42-]=[PO43-] mostly [PO43-] There is are no concentrations provided for the question so it is a question on what stage of deprotonation the phosphoric acid is at
Phosphoric acid has three titratable hydrogen ions; the respective equilibria are expressed as follows: - HBP04 H+ + H2P04 pK1 = 2.1 H2P041- H++ HPO42- pK2 = 6.8 HP042. 2 H++ P043- pK3 = 12.4 How would you prepare 1L of a 1 M phosphate buffer, pH 7.5? Your available chemicals include solid NaH2P04, solid Na2HP04solid NaQH, and 6 M HCl solution. Indicate how you would prepare this buffer using each of the three methods
2) Calculate the pH of 0.08 M Na2HPO4 H3PO4 S H+ + H2 PO4 pK1 = 2.1 H2PO4 5 H+ + HPO42- pK2 = 7.2 HPO42- 5 H+ PO43- pK3 = 12.3
3) Calculate the pH of a solution by mixing 50.0 mL of 0.200 M Na2HPO4 with 20.0 mL 0.0400 M NaH2PO4. (Hint: Buffer solution. Use Henderson-Hasselbalch equation) H3PO4 5 H+ + H2PO4 pkı = 2.1 H2PO4 5 H+ + HPO42- pK2 = 7.2 HPO42- 5 H+ PO43- pK3 = 12.3
Calculate the weight of citric acid – H2O (MW = 210 g/mol) and NaOH (MW 40g/mol) needed to prepare 1.0 L of citrate buffer which is 0.2 M in Na+ and pH 5.2 (pK1= 3.13, pK2= 4.76, pK3= 6.4. Answers: 24.2 g citric acid – H2O and 8.0 g NaOH
What is the initial pH expected for a 0.1 M solution of phosphoric acid (H3PO4)? For 30.0 mL of 0.1 M H3PO4 (aq), what volume of 0.1 M NaOH (aq) is required to fully titrate all three protons to their end points? In the titration of a weak acid with a strong base, how is the half equivalence point determined and what is its significance? How are the pKa and Ka of the weak acid determined from the half equivalence...
5. Calculate the pH at 25°C of a 0.85 M aqueous solution of phosphoric acid (H3PO4). 5. (Ka1, Ka2, and Ka3 for phosphoric acid are 7.5 × 10−3, 6.25 × 10−8, and 4.8 × 10−13, respectively.)
22. The pH of 100 ml of 0.1 M phosphoric acid is 2.5, sketch the titration curve obtained by titrating the phosphoric acid solution with 0.2 M sodium hydroxide. Show clearly how you calculate the values used to plot the curve. (Use Ka values given in no. 15)
4. What molar ratio of HPO4 2-to H2PO4-in solution would produce a pH of 7.0? Phosphoric acid (H3PO4), a triprotic acid, has 3 pKa values: 2.14, 6.86, and 12.4. Hint: Only one of the pKa values is relevant here. 5. For a weak acid with a pKaof 6.0, calculate the ratio of conjugate base to acid at a pH of 5.0. 6. Which of these compounds would be the best buffer at pH 5.0: formic acid (pKa 3.8), acetic acid...
A 0.1 mol/L hydrochloric acid solution has a pH of 1.0 while a 0.1 mol/L hydrofluoric acid solution has a pH of 2.1. If these two acids have the same concentration, why is there a difference in the pH of these solutions?