Q55
dG = dH - T*dS
dG = -98.8 -298*-141.5/1000
dG= -56.633 kJ/mol
choose B
Q56
dG = 2SO 3- (2SO2 + O2)
-142 = 2*-371 - (2*SO2 + 0)
SO2 =( -142 - 2*-371)/-2
dG-SO2 = -300
choose D
Q57
given that dG becomes more possitive as T increases, then
dG =H -T*dS
h must be negative,
as T increases, dG becomes more positive, so dS must be negative
then
dH <0, dS < 0
What is the value of△Go at Amn 25 °C for the reaction -98.8 kJTmo 1-1 141.5...
13. 10. Using Hess' law, what is all at 25°C for the following reaction? CIF() + F:(8) - CIF(e) 2CIF) +0.(g) C12O(g) + OF:) A +167.41J mol 2CIF:(e) +20=(8) -- CLO(g) +30F:(8) A +341.46 mol 2F:() +O )-20F.) A -43.4 kJ/mol A 217.5 kJ/mol B. -130.2 kJ/mol c. 217.5 kJ/mol D. -108.7 kJ/mol 465.4 kJ/mol E 11. What is all for the following reaction? 2H:02(1)→ 2H30(1) - O:(8) APKH:O()) --285.8 kJ/mol; AH® (H:0 (D) - -187.6 kJ/mol A.-196.4 kJ/mol B....
Using enthalpies of formation
(Appendix C), calculate ΔH ° for the following reaction at 25°C.
Also calculate ΔS ° for this reaction from standard entropies at
25°C. Use these values to calculate ΔG ° for the reaction at this
temperature. COCl2(g) + H2O(l ) h CO2(g) + 2HCl(g).
Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kW/mol) 0 AG: (kJ/mol) 0 S° (J/mol-K) 20.87 ΔΗ, (kJ/mol) -946.3 - 33422 AG; {kj/mol) --859,3 -2793 (J/mol-K)...
A-D
9. Use the data given below for the following reaction at 25 C. Fe 04 (s)+ 4 H2(g) 3 Fe (s) + 4 H2O (1), (12+4+4+10-30) Fe Oa(S) 146.4 APH (kJ/mol) -1118.4 H:(g) 130.6 H2O(I) Fe(s) 27.28 S' (J/K/mol) 69.61 -285.83 0 (5+5+2+5=12) (a) Calculate AS,ys, AS,urr, ASuniy and AG at 25°C. ASy's Hh 172 (b) Is the reaction spontaneous at 25°C from entropic point of view? (4) (c) Is the reaction spontaneous at 25°C from free energy point...
1: Consider the following set of data ccollected for a reaction of the form A --> products. time (seconds) [A] (M) 0 1.000 10 0.641 20 0.472 30 0.373 40 0.309 50 0.263 A: What is the average rate of the reaction for the first 10 seconds? rate = ___ M/s B: What is the average rate of the reaction between 30 and 40 seconds? rate = ___ M/s 2: Consider the dimerization of C4H6: 2 C4H6 --> C8H12 for...
(7 pts.) Calculate the heat absorbed when 4.20 g of H2 are produced according to the following equation. CH3OH (g) → CO(g) + 2 H2(g) AH = 90.2 kJ (7 pts.) When one adds 1.475 kJ of heat energy to a sample of gold, the temperature goes from 12.5 °C to 84.6 °C. Calculate the mass of the sample of gold. Gold has a specific heat capacity of 0.129 J/g.°C. (6 pts.) 10. Write the thermochemical equation for the standard...