Predict the major organic products of the following reactions.
1-bromobutane + sodium cyanide in acetone
2-hydroxy-3,3-dimethylbutane in HI
1-chloro-1-methylcyclohexane + NaOH/H2O
1- chloro-1-methylcyclohexane + KOC(CH3)3, HOC(CH3)3
Predict the major organic products of the following reactions. 1-bromobutane + sodium cyanide in acetone 2-hydroxy-3,3-dimethylbutane...
Complete the following reactions and state the
dominant mechanism
acetone b. (R)-2-bromobutane + Nash mechanism: c. (18,2S)-1-bromo-1,2-diphenylpropane methanol + NaOCH; mechanism: d. 3-chloro-2,2-dimethylbutane + NaSCH; mechanism: t-BuOH e. 2-chloro-2-methylpentane + (CH3),CONa H).CoNa BUCH mechanism:
Predict the major organic product of products of each of the following reactions. a) (CH),CHCH-CH- H2SO4 HO b) (CH3),CHCH=CH, 1. Hg(OAc), H2O 2. NaBH 1. BH3-THF c) (CH3),CHCH=CH2 2. H2O3, NaOH
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Predict the major organic product or products of each of the following reactions. H2SO4 a) (CH3),CHCH-CH2- 1. Hg(OAc), H,0 2. NaBH4 b) (CH3)2CHCH=CH, 1. BH3-THF 2. H2O2, NaOH c) (CH3)2CHCH=CH2
Predict the major products for each of the following reactions.
KOC(CHsh HOC(CH3)hs HBr H20, H2SO4, 100 C H PO4. conc -0109%0 60 100 C
ROBLE Predict the major products of the following reactions 22-5 (a) acetone )LDA (2) CH2-CHCH2Br (1) LDA (2) CH3I (1) LDA (2) CH3CH2I
ROBLE Predict the major products of the following reactions 22-5 (a) acetone )LDA (2) CH2-CHCH2Br (1) LDA (2) CH3I (1) LDA (2) CH3CH2I
2. Predict the major organic product(s) of the
reactions below. Assume 1 equivalent of reagent unless otherwise
stated, it's a solvent, or an oxidizing/reducing agent. Do consider
stereochemistry and regioselectivity.
2. Predict the major organic product(s) of the reactions below. Assume 1 equivalent of reagent unless otherwise stated, it's a solvent, or an oxidizing/reducing agent. Do consider stereochemistry and regioselectivity. (3 points each; 15 points total) A. Me 1. HNO3 2. O3 3. DMS 1. mCPBA, DCM (1 equiv) 2....
For the following reactions, predict the MAJOR product(s). If a pair of enantiomers is expected, draw both enantiomers. NaSH Cis-1-bromo-3-methylcyclohexane acetone OTs 1. NaI/acetone 2. NaCN/DMF CH3 NaCN H,с. Br CH3 Бшн.
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...
Part 2. Predict the Organic Products. Predict the major organic product(s) for each of the following reactions. Be sure to show stereochemistry when appropriate. (3 points each) 1) NaNH / NH3 2) CH31 1) BH3 / THE 2) H2O2/NaOH/H20 1) OsO4 / THE 2) Has | 1) NaNH / liq. NH3 2) H20