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8. Use the image to answer the questions that follow HO-CH HO-CH2 HO-CH2 CHO H₂o OH CHO CHO OCH CHOICH CH-OH CHCc CHOICH CH 10 | | CH-CH HỒ CH-CH CH-CH CH-CH CH-CH но он но HO он но OH OH HO A B C D Do not e How many carbons does each of the above sugars contain? Name to E n ipo Which sugars are aldoses and which are ketoses? Identify each sugar. Name the linkage for each...
complete the reactions
Br2, H2O CHO HO EH H-OH H-OH НО- CH2OH T ЕН O CNH2 1) Brą, NaOH, H20 O 2) (CH3)2CHCCI, pyridine
draw the major product
14. HNO, CHO Но+н H-HOH H-HOH HO+H CH2OH 15. oo HNcO; 1) (CH3),COCOCOC(CH3) 3 o N:C:NH/ Ph сно HOTH PHNHNH2 16. HOH (3 equiv.) H +OH HO+H CH2OH
CHO H-C-OH H-C-OH H-C-OH CH, OH CHO 1 H-C-OH HO-c-H H-C-OH H-C-OH CH, OH CHO H-C-OH HO-C-H HO-º-H H-C-OH CH,OH CH,OH CEO HO-C-H H-C-OH H-C-OH CH,OH D A B с Which of the sugars in the figure above is an ketopentose? C B None of the choices are correct. D A
оо 15. H2N CO2 1) (CH3)3COCOCOC(CH3)3 아 2) -N:CENA CHO HO+H PhNHNH | 16. H -OH (3 equiv.) HO -H H- CH2OH -OH
CHO HO+H PhNHNH2 H OH (3 equiv.) H-OH HO+H CH2OH
transformation
OAc OAc AcO Aco Aco OCH2CH2Ph OAc OAc e) CHO OH 1. HCN 2. H17/H20 3. Na/Hg но CH2OH
OAc OAc AcO Aco Aco OCH2CH2Ph OAc OAc e) CHO OH 1. HCN 2. H17/H20 3. Na/Hg но CH2OH
CHGOH c=o OH H- C=0 HOW H- OH Ho+H HOM онон H CH.CH CH OH CH OH sorbose xylulose wylo D isomer L isomer OH OH CH3 -CH-CH CH-CH CH3 -CH2-C-CH3 CH Scree 2019-12 Chiral Achiral Student F ion_Han...
D-Glucose RC +HO-R = H----OH HOP! H -OH нон CH, OH "CH, OH OH HOROR R-C-OR R -C-OR + HOH H HO-R Hemiacetal Acetal Aldehyde Alcohol OR 3-436- OHHO- --OR = R'--0 + HO- R R RC-OR + HOH HOR Ketone Alcohol Hemiketal Ketal ch Wired Company CH, OH Сен,он 5. Label the functional group as acetal, ketal, hemiacetal or hemiketal. KOH OH нон a-D-Glucopyranose B-D-Glucopyranose
-UN cho HO HO OH Онст CH2OH он бн HO Loan Is -OH Br enant Same CH,OH (13) Rank the hydrogen atoms indicated with a letter in order of increasing ease of removal to form a carbocation (1 = easiest to remove, 3 = hardes to remove). Explain your ranking. (3 pts) I because there is Resonance нсъсн 2 becau& there is only one t to remove H-CH2-0-CH-CH3 I before doing Raphaule HH 3 because there are two Carber that...