Homework Answers
| Methyl | singlet in proton NMR |
| ethyl | methylene will be quartet and methyl will be a triplet |
| isopropyl | CH will be multiplet and two methyls will be a doublet |
| propyl | terminal CH2 and CH3 will be triplet and central CH2 will be multiplet |
| tert-butyl | three methyl group will be a singlet |
The above signal will appear in proton NMR.
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- What would the spectrum look like for each of the following branches? A. Methyl B....
9.4 Draw a structural formula for each of the following esters: a. cyclohexyl propanoate b. methyl...
9.4 Draw a structural formula for each of the following esters: a. cyclohexyl propanoate b. methyl formate e, ethyl benzoate d. isopropyl acetate e. butyl butanoate f. propyl pentanoate 9.5 Assign names to each of the following amines: NH b. CH, -NH-CH2-CH c. (CH-CH2),N 4. NH - CHE 6, CHỊCH,CH, NH, 9.6 Complete the following equations: a. CH CH NH2 + HCI NH b. + HCI C. CHỊCHÚNH - CHI + HBr + d. N(CH)2 + HBr - 9.7 Draw...
26) Name the following compound. CH3 H2C=CH-CH2CHCH: A) 1,1-dimethyl-3-butane B) 4-methyl-1-pentene C) hexene D) 2-methyl-4-pentene E)...
26) Name the following compound. CH3 H2C=CH-CH2CHCH: A) 1,1-dimethyl-3-butane B) 4-methyl-1-pentene C) hexene D) 2-methyl-4-pentene E) 2-methylpentene 27) Name the following compound. CI A) 2,3,5-trichlorobenzene B) trichlorostyrene C) 1,3,4-trichlorobenzene D) 1,3,4-trichlorohexene E) 1,2,4-trichlorobenzene 28) Identify the formula for an alkene. A) CnH2n+4 B) CnH2n+2 C) CnH2n D) CnH2n-4 E) CnH2n-2 29) Name the following compound. A) 1,4-bromocyclohexene B) 1,4-dibromobenzene C) 3,6-dibromobenzene D) 2,5-dibromobenzene E) 2,5-dibromocyclohexene 30) Name the following compound. CECH CH,CH,CHCH A) 2-ethynebutane B) 3-methyl-1-pentyne C) 3-methyl-4-pentyne D) 3-ethyl-1-butyne...
Homework Problems 8.1 Draw the structural formula for each of the following: a. 5-chloro-4-methyl-2-hexanol b. 2,3-dimethylcyclopentanol...
Homework Problems 8.1 Draw the structural formula for each of the following: a. 5-chloro-4-methyl-2-hexanol b. 2,3-dimethylcyclopentanol c. 5,5-diethyl-1-heptanol d. 2-ethyl-4-isopropylcyclohexanol e. 4-ethylphenol f. 2-nitrophenol g. cyclopropyl methyl ether h. isopropyl propyl ether 8.2 Give the product for the dehydration of each of the following alcohols. CH-CH2-CH3 a. ОН b. ОН C. OH d. 8.3 What product would result from the oxidation of each of the following alcohols? Write the chemical equations. a. 2-butanol b. 2-methyl-2-pentanol c. cyclohexanol d. 3-ethylcyclopentanol Name...
What is the name for this three-carbon alkyl group? CH-CH-CH, O butyl propyl methyl O ethyl...
What is the name for this three-carbon alkyl group? CH-CH-CH, O butyl propyl methyl O ethyl O isopropyl
9.19 Draw structures corresponding to the following names: (b) 3-Ethyl-5-methyl-1,6,8-decatriyne ...
Draw structures corresponding to the following names:
9.19 Draw structures corresponding to the following names: (b) 3-Ethyl-5-methyl-1,6,8-decatriyne (a) 3,3-Dimethyl-4-octyne (c) 2,2,5,5-Tetramethyl-3-hexyne (d) 3,4-Dimethylcyclodecyne (e) 3,5-Heptadien-1-yne (g) 3-sec-Butyl-1-heptyne (f) 3-Chloro-4,4-dimethyl-1-nonen-6-yne (h) S-tert-Butyl-2-methyl-3-octyne
9.19 Draw structures corresponding to the following names: (b) 3-Ethyl-5-methyl-1,6,8-decatriyne (a) 3,3-Dimethyl-4-octyne (c) 2,2,5,5-Tetramethyl-3-hexyne (d) 3,4-Dimethylcyclodecyne (e) 3,5-Heptadien-1-yne (g) 3-sec-Butyl-1-heptyne (f) 3-Chloro-4,4-dimethyl-1-nonen-6-yne (h) S-tert-Butyl-2-methyl-3-octyne
eneral classification is given to the molecule below? A) primary chloride B) secondary chloride C) tertiary...
eneral classification is given to the molecule below? A) primary chloride B) secondary chloride C) tertiary chloride D) vinyl chloride E) benzyl chloride 12. 13) Which of the following is a geminal dihalide? A) cis-1,2-dibromocyclopentane B) 3,3-dichloropentane C) trans-1,4-diiodocyclohexane D) isobutyl chloride E) 1,3-dibromoheptane 13. 15) Which of the following is a secondary alkyl halide? A) methyl bromide B) isopropyl chloride C)-butyl iodide D) propyl bromide E) isobutyl chloride 14. 17) What is the IUPAC name of the compound shown...
classify each of the following as a primary CH-CHE The compound CH -CH-CH-CH-COOH is called a...
classify each of the following as a primary
CH-CHE The compound CH -CH-CH-CH-COOH is called a 3-hexanoic acid b. 2-ethyl pentancate C. 2-ethyl pentanoic acid d. 3-heptanoic acid e 4 -heptanoic acid (ioni 2 Fien) 5. Which equation correctly represents the dissociation of a carbovie acid? CH - -OH a CH-COOH + HO-CHY-COOH, OH b. CHY-COOH-CH.COO + H,0 c CH-COOH + H2O - CH-COO + H,09 d. CHỊ-COOH + HBO - CH2-COOH + MO e CH-COOH +24,0 - CH-C00+ 2H,0*...
A molecule was incorrectly named 3-n-butyl-5-ethyl-4-isopropylhexane. The correct name would be: OA) 1-sec-butyl-2-ethyl-1-isopropylhexane O B) 3-sec-butyl-4-ethyl-2-methyl-octane...
A molecule was incorrectly named 3-n-butyl-5-ethyl-4-isopropylhexane. The correct name would be: OA) 1-sec-butyl-2-ethyl-1-isopropylhexane O B) 3-sec-butyl-4-ethyl-2-methyl-octane OC) 6-isopropyl-5-diethyl-7-methylnonane O D) 5-ethyl-4-isopropyl-3-methylnonane OE) 4-n-butyl-2,2-diethyl-3-isopropylhexane
1. What is the IUPAC name for the following compound? CH3 CI CH3-CH-C- CH-CH CH3 CH3...
1. What is the IUPAC name for the following compound? CH3 CI CH3-CH-C- CH-CH CH3 CH3 A) 4-chloro-4,5-dimethyl-2-hexene B) 3-chloro-1,3,4-trimethyl-1-pentene C) 3-chloro-2,3-dimethyl-4-hexene D) 3-chloro-2,3,5-trimethyl-4-pentene E) 3-chloro-1,3,4,4-tetramethyl-1-butene 2. Name the following compound. CH-CH2 CH,CH CH CCH H-CH A) 2,2-diethylpenatane B) 2,2-diethylpentene C) 4-ethyl-4-methyl-5-hexene D) 3-ethyl-3-methyl-1-hexene E) 4-ethyl-4-methylhexane 3. Name the following compound. CH CH CH, CH,CH CC CH CH2CH CH A) 3-butyl-3-propyl-1-pentyne B) 3-butyl-3-propyl-4-pentyne C) 3-ethyl-3-propyl-1-heptyne D) 5-ethyl-5-propyl-6-heptyne E) 3-ethyl-3-butyl-1-hexyne
5. Which compound in each of the following pairs, if either, would have the higher solubility...
5. Which compound in each of the following pairs, if either, would have the higher solubility in water? your answers briefly a) propane or ethanol b) ethanol or eicosane (CoH42) (Wikipedia will give you the BP for both. This is the only question you need to look up BP's for.) b) 2-butanol or 2-heptanol c) ethyl propyl ether or 1-pentanol d) diethyl ether or 1-decanol e) 1-butanol (aka n-butyl alcohol) and +butyl alcohol
9.4 Draw a structural formula for each of the following esters: a. cyclohexyl propanoate b. methyl formate e, ethyl benzoate d. isopropyl acetate e. butyl butanoate f. propyl pentanoate 9.5 Assign names to each of the following amines: NH b. CH, -NH-CH2-CH c. (CH-CH2),N 4. NH - CHE 6, CHỊCH,CH, NH, 9.6 Complete the following equations: a. CH CH NH2 + HCI NH b. + HCI C. CHỊCHÚNH - CHI + HBr + d. N(CH)2 + HBr - 9.7 Draw...
26) Name the following compound. CH3 H2C=CH-CH2CHCH: A) 1,1-dimethyl-3-butane B) 4-methyl-1-pentene C) hexene D) 2-methyl-4-pentene E) 2-methylpentene 27) Name the following compound. CI A) 2,3,5-trichlorobenzene B) trichlorostyrene C) 1,3,4-trichlorobenzene D) 1,3,4-trichlorohexene E) 1,2,4-trichlorobenzene 28) Identify the formula for an alkene. A) CnH2n+4 B) CnH2n+2 C) CnH2n D) CnH2n-4 E) CnH2n-2 29) Name the following compound. A) 1,4-bromocyclohexene B) 1,4-dibromobenzene C) 3,6-dibromobenzene D) 2,5-dibromobenzene E) 2,5-dibromocyclohexene 30) Name the following compound. CECH CH,CH,CHCH A) 2-ethynebutane B) 3-methyl-1-pentyne C) 3-methyl-4-pentyne D) 3-ethyl-1-butyne...
Homework Problems 8.1 Draw the structural formula for each of the following: a. 5-chloro-4-methyl-2-hexanol b. 2,3-dimethylcyclopentanol c. 5,5-diethyl-1-heptanol d. 2-ethyl-4-isopropylcyclohexanol e. 4-ethylphenol f. 2-nitrophenol g. cyclopropyl methyl ether h. isopropyl propyl ether 8.2 Give the product for the dehydration of each of the following alcohols. CH-CH2-CH3 a. ОН b. ОН C. OH d. 8.3 What product would result from the oxidation of each of the following alcohols? Write the chemical equations. a. 2-butanol b. 2-methyl-2-pentanol c. cyclohexanol d. 3-ethylcyclopentanol Name...
What is the name for this three-carbon alkyl group? CH-CH-CH, O butyl propyl methyl O ethyl O isopropyl
Draw structures corresponding to the following names:
9.19 Draw structures corresponding to the following names: (b) 3-Ethyl-5-methyl-1,6,8-decatriyne (a) 3,3-Dimethyl-4-octyne (c) 2,2,5,5-Tetramethyl-3-hexyne (d) 3,4-Dimethylcyclodecyne (e) 3,5-Heptadien-1-yne (g) 3-sec-Butyl-1-heptyne (f) 3-Chloro-4,4-dimethyl-1-nonen-6-yne (h) S-tert-Butyl-2-methyl-3-octyne
9.19 Draw structures corresponding to the following names: (b) 3-Ethyl-5-methyl-1,6,8-decatriyne (a) 3,3-Dimethyl-4-octyne (c) 2,2,5,5-Tetramethyl-3-hexyne (d) 3,4-Dimethylcyclodecyne (e) 3,5-Heptadien-1-yne (g) 3-sec-Butyl-1-heptyne (f) 3-Chloro-4,4-dimethyl-1-nonen-6-yne (h) S-tert-Butyl-2-methyl-3-octyne
eneral classification is given to the molecule below? A) primary chloride B) secondary chloride C) tertiary chloride D) vinyl chloride E) benzyl chloride 12. 13) Which of the following is a geminal dihalide? A) cis-1,2-dibromocyclopentane B) 3,3-dichloropentane C) trans-1,4-diiodocyclohexane D) isobutyl chloride E) 1,3-dibromoheptane 13. 15) Which of the following is a secondary alkyl halide? A) methyl bromide B) isopropyl chloride C)-butyl iodide D) propyl bromide E) isobutyl chloride 14. 17) What is the IUPAC name of the compound shown...
classify each of the following as a primary
CH-CHE The compound CH -CH-CH-CH-COOH is called a 3-hexanoic acid b. 2-ethyl pentancate C. 2-ethyl pentanoic acid d. 3-heptanoic acid e 4 -heptanoic acid (ioni 2 Fien) 5. Which equation correctly represents the dissociation of a carbovie acid? CH - -OH a CH-COOH + HO-CHY-COOH, OH b. CHY-COOH-CH.COO + H,0 c CH-COOH + H2O - CH-COO + H,09 d. CHỊ-COOH + HBO - CH2-COOH + MO e CH-COOH +24,0 - CH-C00+ 2H,0*...
A molecule was incorrectly named 3-n-butyl-5-ethyl-4-isopropylhexane. The correct name would be: OA) 1-sec-butyl-2-ethyl-1-isopropylhexane O B) 3-sec-butyl-4-ethyl-2-methyl-octane OC) 6-isopropyl-5-diethyl-7-methylnonane O D) 5-ethyl-4-isopropyl-3-methylnonane OE) 4-n-butyl-2,2-diethyl-3-isopropylhexane
1. What is the IUPAC name for the following compound? CH3 CI CH3-CH-C- CH-CH CH3 CH3 A) 4-chloro-4,5-dimethyl-2-hexene B) 3-chloro-1,3,4-trimethyl-1-pentene C) 3-chloro-2,3-dimethyl-4-hexene D) 3-chloro-2,3,5-trimethyl-4-pentene E) 3-chloro-1,3,4,4-tetramethyl-1-butene 2. Name the following compound. CH-CH2 CH,CH CH CCH H-CH A) 2,2-diethylpenatane B) 2,2-diethylpentene C) 4-ethyl-4-methyl-5-hexene D) 3-ethyl-3-methyl-1-hexene E) 4-ethyl-4-methylhexane 3. Name the following compound. CH CH CH, CH,CH CC CH CH2CH CH A) 3-butyl-3-propyl-1-pentyne B) 3-butyl-3-propyl-4-pentyne C) 3-ethyl-3-propyl-1-heptyne D) 5-ethyl-5-propyl-6-heptyne E) 3-ethyl-3-butyl-1-hexyne
5. Which compound in each of the following pairs, if either, would have the higher solubility in water? your answers briefly a) propane or ethanol b) ethanol or eicosane (CoH42) (Wikipedia will give you the BP for both. This is the only question you need to look up BP's for.) b) 2-butanol or 2-heptanol c) ethyl propyl ether or 1-pentanol d) diethyl ether or 1-decanol e) 1-butanol (aka n-butyl alcohol) and +butyl alcohol
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