by defintion
work = -pdV
work = - p (Vf - Vi)
given
pressure (p) = 2.7 atm = 2.7 atm x (101325 Pa / 1 atm ) = 273578 Pa
now
Vf = 1.4 L = 1.4 L x ( 10-3 m3 / 1 L ) = 1.4 x 10-3 m3
plug in the values
457 J = -273578 Pa x ( (1.4 x 10-3 )- Vi ) m3
Vi = 3.07 x 10-3 m3
Vi = 3.07 x 10-3 m3 x ( 1000 L / 1 m3)
Vi = 3.07 L
so
the initial volume of the gas is 3.07 L
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