Question

Which of the following compounds, when treated with sodium nitrite in aqueous hydrochloric acid at room temperature, do not generate nitrogen gas?

NHCHa NH2 CH2NH2 N(CH3)2 CH3 3 4 2 A. 2 and 4 only D. 1, 2, and 4 only B. 2 and 3 only E. 2, 3, and 4 only C. 1 and 4 only

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Answer #1

option C is correct

Explanation: Reaction of primary amine with NaNO2, HCl gives diazotization reaction and produces diazonium cation as product. structures 1 and 4 are not primary amines and do not give diazotization reaction.

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