Step 1: find mole fraction of both components
Molar mass of ClF5,
MM = 1*MM(Cl) + 5*MM(F)
= 1*35.45 + 5*19.0
= 130.45 g/mol
Molar mass of N2O,
MM = 2*MM(N) + 1*MM(O)
= 2*14.01 + 1*16.0
= 44.02 g/mol
n(ClF5) = mass of ClF5/molar mass of ClF5
= 16.1/130.45
= 0.1234
n(N2O) = mass of N2O/molar mass of N2O
= 5.21/44.02
= 0.1184
n(ClF5),n1 = 0.1234 mol
n(N2O),n2 = 0.1184 mol
Total number of mol = n1+n2
= 0.1234 + 0.1184
= 0.2418 mol
Mole fraction of each components are
X(ClF5) = n1/total mol
= 0.1234/0.2418
= 0.5105
X(N2O) = n2/total mol
= 0.1184/0.2418
= 0.4895
Step 2: find total pressure
Given:
V = 6.0 L
n = 0.2417742275062609 mol
T = 7.39 oC
= (7.39+273) K
= 280.39 K
use:
P * V = n*R*T
P * 6 L = 0.2418 mol* 0.08206 atm.L/mol.K * 280.39 K
P = 0.9272 atm
Step 3: find partial pressure of both components
p(ClF5) = X(ClF5) * P
= 0.5105 * 0.9272
= 0.4733 atm
p(N2O) = X(N2O) * P
= 0.4895 * 0.9272
= 0.4539 atm
Answer:
mole fraction of ClF5 = 0.510
p(ClF5) = 0.473 atm
mole fraction of N2O = 0.490
p(N2O) = 0.454 atm
p Total = 0.927 atm
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