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#3 please Dlaw lile Uuwig compounds 10r the names presented. (2 pts ea) a. (2S)-2-(4-vinylcyclohexyl)propanoic acid...
(a) Draw the saw-horse (or wedge-dash) projection of (2S,3R)-3-methylpentan-2-ol. [Marks: 1] (b) Draw the Newman projections of the 2-3 bond in (2S,3R)-3-methylpentan-2-ol. [Marks: 2] (c) Based on the Newman projections from part b. - draw a rotation vs. energy diagram (you do NOT need to give specific energy values in this diagram) that will allow you to identify the most stable confirmation around the 2-3 bond. Assume the greatest steric and torsional strain occurs when the hydroxyl and ethyl groups...
Draw the molecules from the IUPAC names: a)(2S)-2bromo-4-methylhexane b)(R,E)-6-aminohept-2-en-4-one c)(1R,3R)-3-methylcyclopentane-1-ol d)(2S,3S)-2,3-dihydroxysuccinic and
please help for part A, B, and C
(a) Make models of the four 2-bromo-3-hydroxybutanal isomers. Accurately sketch them in the boxes. Use solid and dashed wedges where necessary. (2 pts) (b) For each isomer, draw a Newman projection for the most stable conformation of the C(2)-C(3) bond. (2 pts) (c) Use the RIS system to assign the absolute configuration of each chiral (stereogenic) center. (1 pt) Configuration? (2R, 3S) (2s, 3R (2S, 3S) (2R 3R) Configuration? (2R, 3S) (2S,...
Draw the molecules from the IUPAC names: 1. (2 S)-2-bromo-4-methylhexane 2. (1 R, 3R)-3-methylcyclopentan-1-ol 3. (R,E)-6-aminohept-2-en-4-one 4. (2S, 3S-2,3-dihydroxysuccinic acid
9. Treatment of (2R,3S)-2-chloro-3-methylpentane with potassium t-butoxide in t-butanol gives a single stereoisomer of 3-phenyl-2-butene. (15 pts) CI CH, | (CH, CƠ K, CH,CH=C-CH-CH, CHE (CH3),COH Draw the three possible Newman projections of the staggered conformations of (2R,3S)-2- chloro-3-methylpentane. Circle the one Newman projection with the conformation most suited for the elimination reaction. Conformation 2 Conformation 3 Conformation 1 Show the stereoisomer of the product expected from this elimination path.
4) Draw the following compounds a. (2S,5R)-5-chloro-2-ethylhexanoic acid b. (1R,2R,4R)-4-ethylcyclohexane-1,2-diol c. (2S,3R)-3-amino-2-phenylbutanal d. (1S,2S,3R)-2-fluoro-3-propylcyclobutanol e. (2E, 7Z)-5-bromo-2,7-nonadiene
Draw the structures for the following compounds. a) (3Z,5S)-4-bromo-5-chloro-2-methylhexa-1,3-diene b) (5S,7S)-5-(bromomethyl)-7-chloro-oct-2-yne c) (1S,5S,6S)-6-bromo-5-[(1R)-1-chloroethyl]cyclohex-3-enol d) 2-bromo-4-[(1R)-1-hydroxyethyl]benzoic acid e) (3S,4S,5S)-5-amino-3-hydroxy-4-methylhexanal f) (Z,2R,4R)-6-bromo-4-chloro-N-ethyl-N-methylhept-5-en-2-amine g) [(1S)-1-chloroethyl] (Z,3R)-5-chloro-3-methoxyhex-4-enoate h) (Z,3R)-3-bromo-4-chloro-7-methyloct-4-enoic acid i) (3S)-6-bromo-N-ethyl-N,3-dimethylhex-4-ynamide j) (Z,3R,4S)-6-bromo-3-[(1S)-1-chloroethyl]-4-hydroxyhept-5-en-2-one
1. (a) Draw the two chair conformations for this molecule. (3 pts) (b) Label the more stable conformation (1 pt) 2. Provide (RS)-designations for the two starred (1) stereogenic centers (3 pts) 3. Use a Newman projection to draw the most stable conformation for the C(3)-C(4) bond in this molecule. (3 pts) OH 3-fluoro-3-methylpentan-1-ol
9. (10 pts) Draw structures for the following compounds: (a) (2S,4S)-2-Bromo-4,5-diethylheptane (b)(R)-3-hexyn-2-ol
4. Draw structures for the following compounds (12 points): a. 6,6-dimethylhept-2-yne b. 5-amino-4-methoxyhept-6-yn-2-ol c. 4-bromo-4-methyl-2-cyclohexenol d. (S)-2-chlorohexane e. (2S,3S)-2,3-butanediol f. (R)-3-bromocyclopentene