Self-test 17A.2 The initial rate of a certain reaction depended on the concentration of a substance J as follows:
[J]0/(10−3 moldm−3 ) 5.0 10.2 17 30
v0/(10−7 moldm−3 s −1 ) 3.6 9.6 4 130
Find the order of the reaction with respect to J and the rate constant.
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Kinetics A level chemistry OCR
tome Insert Draw View Help Picture Open in app U v Avto CIN Evev Summary questions 1 In a reaction between reactants A, B, and C, the rate equation is: rate = [B][C] a State the orders with respect to A, B, and C. (3 marks) b Determine the overall order for the reaction. (1 mark) 2 A reaction is zero order with respect to A, first order with respect to B, and second order...
10 and 11
10. Nitrosyl chloride, NOCI, decomposes slowly to NO and Cl2, the reaction follows second order kinetics with a rate constant of 0.020 L mol-' s at a certain temperature. 2 NOCI (g) → 2 NO(g) + Cl2(g) If the initial concentration of NOCI in a closed reaction vessel is 0.050 M, what will be the concentration be after 30 minutes? 11. The reaction 2 NO2 (g) → 2 NO(g) + O2(g), is second order with respect to...
The reaction, A → products, is known to be
zeroth order with respect to the concentration of A and zeroth
order overall. The rate constant for the reaction is 0.0750
M·hr-1 at a certain temperature.
If the initial concentration of A is 0.875 M. What will be the
concentration of A after 10.0 hr?
Answer M
How long would it take for 80.0% of the starting material (A) to
undergo reaction?
Answer hr
The reaction, A → products, is known...
The rate law for a certain enzymatic reaction is zero order with respect to the substrate. The rate constant for this reaction is 4.6 times 10^2 M middot s^-1. If the initial concentration of the substrate is 0.338 mol L^-1, what is the initial rate of the reaction? rate = _______ times 10 _______ M middot s^-1
For the reaction A+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. The following data were collected: Trial [A] (M) [B] (M) [C] (M) Initial rate (M/s) 1 0.40 0.40 0.40 1.2×10−4 2 0.40 0.40 1.20 3.6×10−4 3 0.80 0.40 0.40 4.8×10−4 4 0.80 0.80 0.40 4.8×10−4 Rate law equation The rate of a chemical reaction depends on the concentrations of the reactants. For the general reaction between A and B, aA+bB⇌cC+dD The dependence of the...
1. For a first order k = 9.09x10-3 1/s. If the initial concentration is 7.06 M calculate the concentration after 35.0 s. 2. How long does it take the initial concentration of 0.778 M reduce to 0.453 M when k for the first order reaction is 2.11x10-2 1/min.? 3. The rate constant for a reaction at 25.0 oC is 2.87x10 -2. What is the rate constant at 55.0 oC? E a= 20.5 kJ. 4. The decomposition of a substance is...
9,10,11
9. Consider the decomposition reaction of N2Os. 2 N203(g) → 4NO2(g) + O2(g) follows the first order kinetics with rate constant of 4.8 x 10's. (a) if the initial 165 x 10-2M what is the concentration at 825 s? (b) How long it will take for concentration is 1.65 x 10-2M what is the concentrat the concentration of N2Os to decrease to 1.00 x 10-2M? t 10. Nitrosyl chloride, NOCI, decomposes slowly to NO and Cl2, the reaction follows...
1) Consider the reaction Under certain specified conditions, the rate of the reaction is: (a) What is the order of the reaction with respect to the concentration of oxygen? (b) What is the overall order of the reaction? (c) If the concentration of hydrogen is doubled, will the rate of the reaction remain unchanged double, quadruple, or be halved? 2) For the reaction the rate of the reaction was increased by a factor of eight when the concentration of both...
For the reaction A+B+C→D+E, the initial reaction rate was measured for various initial concentrations of reactants. The following data were collected: Trial [A] (M) [B] (M) [C] (M) Initial rate (M/s) 1 0.40 0.40 0.40 1.2×10−4 2 0.40 0.40 1.20 3.6×10−4 3 0.80 0.40 0.40 4.8×10−4 4 0.80 0.80 0.40 4.8×10−4 Rate law equation The rate of a chemical reaction depends on the concentrations of the reactants. For the general reaction between Aand B, aA+bB⇌cC+dD The dependence of the reaction...
The integrated rate law allows chemists to predict the reactant concentration after a certain amount of time, or the time it would take for a certain concentration to be reached. The integrated rate law for a first-order reaction is: [A]=[A]0e−kt Now say we are particularly interested in the time it would take for the concentration to become one-half of its initial value. Then we could substitute [A]02 for [A] and rearrange the equation to: t1/2=0.693k This equation calculates the time...