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I. What is the heat capacity of 185g of liquid water? How many Kilojoules are needed to raise the temperature of 10 kg of liquid water from 24.6°C to 46.2°C and 38.5 mol of water from 38.1°C to 79.4°C? Ans: 774.04J/gC, 903.74Kj, 119.75KJ 2. A 2.200 g sample of quinone, C&402. is burned in a bomb Calorimeter whose total heat capacity is 7.854 kJ C. The temperature of calorimeter increases from 23.44°C to 30.57C. What is the heat of combustion per gram of quinone? Per mole of quinone? S 3. From the data below for the reaction NO2+CO- NO+ CO2, give the rate law and the lue of the equilibrium constant K. The value of the initial rate when [NO] .-.75M and [CO]o 20M is what? Trial No NO2] [CO initial rate, M/s 0.40M 3.1 10 2. 3. Ans: Rate K [NO,] K-4.96 101, Initial Rate-2.79 10 0.25M 0.25M 0.80M 3.1 10 0.50M 0.80M 1.210 4. What is the pH of a 0.040 M solution of HCIOs and 0.011 M solution of Ca(O1H)2. 5 Ans: 1.40, 12.04 5. A student prepared a 0.10 M solution of formic acid, HCHO, and found its plI at 25°C equal to 2.38. Calculate Ka for formic acid at this temperature. 5 Ans: 1.81+10 6. Calculate the fluoride ion concentration and pH of a solution containing 0.10 mol of HCI and 0.20 mol of HF in 1 L of solution. Ka for HF equals 6.8 10-. 5 Ans: pH 994,F-]-00133 7. A buffer is made by adding 0.300 mol HC2H O2 and 0.300 mol NaC2H302 to enough water to make 1.00L of solution. The pH of the buffer is 4.74. Calculate the pH of this solution (a) after 0.020 mol of NaOH is added (neglect any volume change); (b) after 0.020 mol of HCl is added (again, neglect volume changes).Ka-1.8x10. 5 a) pH 4.8, b) pH-4.68 8. IfKc 6.4x107 for 2C02 (g)-+2C0 (8)+ 0: (8), what is the equilibrium concentration of CO formed from .350M CO2. What is the value of Kp at room temperature. (R .0821) [CO] 6.7*10, Крс 1.57* 10.5 9. For the reaction N2 (g)+3H2 (g)- 2NHs (g) 8GP of NH, is -16.,66 kJ/mol. Calculate 6G, and 6G at 298 K for a reaction mixture that consists of 1 atm N2, 3 atm H2 and ,0.50 atm NHs, R 8.314 J/mol.K

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