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5. For each of the following questions, provide the missing reagents and conditions or predict the...
5. For each of the following questions, provide the missing reagents and conditions or predict the MAJOR product. Indicate stereochemistry and identify a racemic mixture if applicable. If no reaction ocCurs, write out "no reaction." (48pts) a. Br Br b. I) LDA/THF/cold 2) iodomethane / THF 3) NABH,/ MeOH C. I. KCr,O,/H2SO, I. CH CH),N(CH,),сH, (followed by H,O 3-рentanol d. I. NaOH/EtOH II. 1-bromo-4-methylhexane / DMSO I. NaOH/EtOH IV. benzoyl chloride v. I) LIAIH 2) H,O NH e. суclopentanone f....
For each of the following questions, provide the missing reagents (that can be purchased) and conditions or predict the MAJOR product. Indicate stereochemistry and identify a racemic mixture if applicable. If no reaction occurs, write out "no reaction." . a. d. Ag,O/NH,OH "ОН e. 1) CH (CH,),Br/ 2 Li 2) HCI f но но но. (:) g. н NH NH
1. For each of the following questions, provide the missing reagents that can be purchased) and conditions or predict the MAJOR product. Indicate stereochemistry and identify a racer mixture if applicable. If no reaction occurs, write out "no reaction." a 1) LiAlH 2) H.O NaBH / MeOH si -
1) 2 (CH3),CHCH Br / Cul/ 4 Li? CHỊCH, CHỊCH 2) H30+ 2. Using any necessary reagents, show how the following synthetic transformations may be achieved. Give reagents and conditions for each step. Include all synthetic intermediates compounds produced during the course of multi-step synthesis). NOTE: You may not use HOC OH 1. For each of the following questions, provide the missing reagents that can be purchased) and conditions or predict the MAJOR product. Indicate stereochemistry and identify a racemic...
Question 6, Contd... Provide the missing major organic products or reagents/conditions for the following reactions. Unless indicated otherwise, do not forget to include stereochemistry as appropriate and INDICATE ANY RACEMIC MIXTURES. OCH3 1 Equiv. CH3NH2 ignore stereochemistry NMez HCI (cat.) heat excess 1. Nat OEt OEt Eto OEt excess 2. H3O+ Ph
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Question 3 (36 pts.) For each of the following reactions: a) Provide the missing major organic product. Pay attention to stereochemistry unless directed otherwise and identify any racemic mixtures using the (1) symbol. c) Assign each reaction as OXIDATION or REDUCTION as appropriate NaBH, ETOH 1. Excess LIAIH 2. H2O nyomas La Na, Cr20;/H,SO/H, Excess PCC/CH_C12 OH Question 4 (22 pts.). Synthesize the target) molecule on the right from the starting molecule the left Give reagents and...
Queston 6 (56 pts.). Provide the missing major organic products, or reagents/conditions, or organic reactants, as appropriate. Do not forget to include stereochemistry as appropriate unless specified otherwise. 2. Hgo :0: :o 1. Na* CN 2. H30* /heat gnore stereochemistry c) :Br: :OH d) 1 Equiv H3C CI: e) Ph h) heat (Aldol reaction)
5. For each of the following reactions, please provide either the missing reagent(s) and condition(s) or the MAJOR product. If a product is racemic, indicate it is so. If no reaction occurs, write out no reaction.
1. For each of the following transformations, provide the missing reagents/conditions, starting material, or major organic products) as appropriate. You may ignore stereochemistry. All transformations requiring you to fill in reagents can be accomplished in two or fewer steps namorangorang NaOH (cat) moldana 1. Cros, pyridine 2. Hicato c. OYO TA Dono 1. Et Cui 2. H* workup 3. NaBH, MOH modello 1. PhMgBr, E1,0 2 H workup 3. conc. H2SO4 Duplication of this problem ser for any purpose other...
II. Reactions: Predict the major organic product(s) or write the appropriate reagents/starting materials for the following reactions. Indicate stereochemistry and regiochemistry when appropriate. Indicate reactions that are expected to result in a racemic mixture of products DBr 1. Н.О, CHCI он HSO, heat кон 1) вн, THF 3. 2) H202. HO 1) Hg(OAc)2, CH,OH 2) NaBH, OH 5. Br2 SH 6. HIO4 OH THF, H2O "он III. Synthesis: Starting from the alkenyl bromide below, devise a synthesis that produces the...