




Please explain the mechanisms of these reactions in detail 0 6. CrO HO OH OH 3....
e phone Propose mechanisms for the following reactions t h roug h radi o od osmans (a) Ph-C-ci + (CH) CHOH - Ph-C-OCH(CH3)2 (b) Ph-C-OCH, NaOH Ph-C-0- + CH,OH HO $ 135 1o slona CH3 OAc - он (D) CH -CH-CH.CH, (R)-butan-2-ol Ac, Tacetic anhydride) CH, CH-CH,CH, 2-butyl acetate
If
a protecting group was not used, what would be the product of the
Grignard reaction?
CHOEt + HO OH P-TOH toluene reflux QO CH -CH CH2 O Et 0 2 O 2 PhMgBr ether 0 0 Ph. Ph. CHIPh HCI, HO acetone reflux CH3 HO CHỊ cold CHỦ CH "Ph MgBr ОН CH; CHAM CH3CH, CHPh
H,Cro SOCI: H,0 Pyridine PCC CH,CI, HIO HR Peroxide 2. H,0,HCI NES CH- - HN CH,I, Zn(Cu) ether 1.0, 2. (CH) KCN HCN 1.00 2. NaHSO, H,0 HO 2. HCI, H20 H.SO 1. BH. THE 2. H,O, NaOH 1. HgOAC), 2,0 2. NaBH, HUNCH, 1. NBH 2. H.O
1. Write the products of the reactions below. I. HO 2. PCC 3.CH, MgBr 4. Hot 1. NaCN 2. H ,H,O 3. SOCI 4. MeOH 1. CH.CH, MgBr 2. H,H,O 3. CHỊCH,CHCO3 CH,CH,OH
Please show all arrows and explain the answer
Predict the Product. Provide the stable organic product(s) for the reactions below. MgBr (1 eq.) von 1. Mgº, CH3CH2OCH2CH3 2. Å 3. H2O, HCI 1. CH,MgBr (xs) 2. H2O, HCI 1. Mg", CH3CH,OCH,CH3 2. D20
Part II: Draw the structure of the major product for each of the following reactions: OH 1) NaBH, OCH, 2) H,0 OH CH O- mi + ,0 — HCC OCH 1) CH,MgBr/ ether 2) H₃0'
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3) KOtBu 2) O 1) NaOH on. Br 2) O o
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он...
Please fill in the boxes for the empty portions of these
reactions.
CH3 OH Q OH OH -MgBr HC сн. сі AICI KMnO,,H,O H2C heat сн. H 636868 CI (CH,CH),Culi |
predict the products of the following reactions
0 () CH,CH CCH,-C-OCH, NocCH (2) CH (3) Ho .heat (I) NaOCH2CH (2) H,O', heat (b) CH,-C-CH-C-OCH,CH,+ CH, (1) LDA -OH (c) Ph CH, () CH,CH,CH,Br (1) H2C-CH CH,Br (2) H0* OCH, NaOCH Ph (2) CH,CH,CH2CH2Br (g) product from part (f) (decarboxylation)
0 () CH,CH CCH,-C-OCH, NocCH (2) CH (3) Ho .heat (I) NaOCH2CH (2) H,O', heat (b) CH,-C-CH-C-OCH,CH,+ CH, (1) LDA -OH (c) Ph CH, () CH,CH,CH,Br (1) H2C-CH CH,Br (2) H0*...
MOBI (1eq.) 1. Mgº, CH.CH,OCH,CH, 2 Å 3. H,O, HCI 1. CH,MgBr(xs) O 2 H,O, HCI 1. Mg. CH,CH,OCH,CH, 2. 0,0