In each of the following reactions, there are 3 numbered steps, for each of which a...
Predict the major organic product or products of each of the
following reactions:
Identify the mechanism taking place in each of the
reactions and please provide explanation.
1. 03 2. Zn/H2O CH,C=CCH, H2 Lindlar's catalyst CH,C=CCH, Li NH3, liquid O3 Zn H2O
13. (15) For each a For each of the following reactions, fill in the missing reagents from the list provided for Wormation of the product shown. Sequential steps, if necessary. should be numbered. Reagents can be used more than once. Reagent List: H2 C H2O2 = NaH PBT OCI NaBH. Pd/C NaOH BH2O HO HgCl2 Pd/Caco, Br2 HBr H2O (HOAC) (MCPBA) (pyridine) (Msch) por -Cl menos de plaqueta don -он i н он
Reactions
Consider the acid-catalyzed hydration of 3-methyl-1-butene. For each of the four steps, add one or two curved arrows to the reactant side to show the mechanism. H CH2- (1) H3C- > HAC- ——H CH3 H |- CH3 红人 - Kr * - 十 CH3 | H3C- ||||| → HAC CH3 CH3 CH3 H (continued below) vap di VöŁH H3C (3) :0-LH / + CH2-CH3 -> H3C- CH2-CH3 CH3 (continued below) 27 E In :01 I- (4) H3c- c Hz-CH3...
Please answer all 3 questions
Which of the following species has en stor that has a partially filled valence shell of electroni? molecular bromine, Bez fluoride anion, ammonia, NH3 aluminum trichloride, AlCl3 QUESTION 43 What reagents are needed to accomplish this reaction? H2/Pt NaBH, MOH Hp/Lindlar's catalyst LI, ENH2, -78 °C followed by aq. NHACI QUESTION 44 The addition of bromine to the alkene shown will give: Br2 one meso compound one pair of enantiomers two meso compounds four stereoisomers
Evening SN2 vs. E2 Homework Predict the major product(s) expected for each of the following reactions. Remember to indica stereochemistry, when appropriate. If no reaction is expected, write NR. a. CH3CN opothe Na t-BuO t-BuOH Rrot b. C. H3C d. H3C Br e. OH EtOH Pro NaN3 OH acetone poic NaOH Stos nlphe h. OTS EtOH pokc
7. (3 pts each) Write the correct reactant, reagents, or major product of the following reactions он TSCI Nal pyridine DMSO HBr EtOK EtOH CH2l2, Zn/Cu Et20 Br2 hv ONa Ph3PBr2 он elimination product Name: Page 6 of
write a major product for each of the following reaction,
indicate appropriate stereochemistry
1. NBS, hv, CC14 Tag 1. Xz; x's NaNH2 2. (CH3)3COK, (CH3)3COH, A 3. OHC = CHO, toluene, A 2. ă Br 3. H2 , Lindlar's catalyst 3. RCOZH; H30°x, H2O 1(x'sNaHz; ~ X (C) = 2. K, NH3(1), CH3CH2OH 3. CH2l2, Zn(Cu)
2) Provide a product for each of the following reactions. Ensure correct chemoselectivity, stereoselectivity and regioselectivity in product determination. OH SOCI (2eq) b) 1.0 2) H2O, NaOH - KMnO., NaOH, H2O H3C 1) Mg 2) CO. 3) H30 ОН Na Cr.O H2SO4, H,0 (excess) NaBH EtOH Hint: esterification H+ DLDA 2) PhCH,Br /4 736
please help asap
Question 3 (36 pts.) For each of the following reactions: a) Provide the missing major organic product. Pay attention to stereochemistry unless directed otherwise and identify any racemic mixtures using the (1) symbol. c) Assign each reaction as OXIDATION or REDUCTION as appropriate NaBH, ETOH 1. Excess LIAIH 2. H2O nyomas La Na, Cr20;/H,SO/H, Excess PCC/CH_C12 OH Question 4 (22 pts.). Synthesize the target) molecule on the right from the starting molecule the left Give reagents and...
Complete all of the following reactions by drawing structures of the major products for each. Where appropriate, clearly indicate stereochemistry of the product. Н, РО, 2 Br 3. (1)OsO (2)NaHSO) Cl2/H2O 5. ()Bн, (2)H,O2OH(a 6- (1O (2)Zn, H 1. CHClyNaOH 8. (1)Hg 2+ (2)NaBH 9. KMnO. HO 10. 41