QUESTION 9
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g):
Step 1: 2NO(g) → N2O2(g) (very fast, reversible)
Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow)
Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast)
What is the rate law for the overall reaction?
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k[N2O][H2] |
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k[NO]2[H2] |
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k[NO]2[H2]2 |
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k[NO]1/2[H2] |
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k[NO]2 |
QUESTION 9 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1:...
QUESTION 19 A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) + N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? Ok[NO]1/2[H2] k[NO]2[H2] k[NO] [H2)2 k[N20][H2] k[NO]2
A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) → N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) → N2O(g) + H2O(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) + H2O(g) (fast) What is the rate law for the overall reaction? O k[no]/2[Hz] O k[N20][H2] O k[NO]2 O k[NO]2[Hz] O k[NO]2[H212
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A proposed mechanism for the reaction 2NO(g) +2H2(g) → N2(g) + 2H2O(g): Step 1: 2NO(g) + N2O2(g) (very fast, reversible) Step 2: N2O2(g) + H2(g) N20(g) + H20(g) (slow) Step 3: N2O(g) + H2(g) →N2(g) +H2O(g) (fast) What is the rate law for the overall reaction? Ok[NO2 Ok[NO]2[H212 O k[NO]2[H2] Ok[N20][H2] k[NO]1/2[H2] 2NO(g) +Cl2 (g) → NOCI (8) Experiment concentration of NO (M) 0.09 0.045 0.045 concentration of Cl2(M) Rate (M/s) 0.01 3.40 x 10-4 8.50 x...
14. The reaction 2 H2(g) + 2 NO(g) ® N2(g) + 2 H2O(g) is proposed to have the alternate mechanism: 2 NO(g) ® N2O2(g) FAST N2O2(g) + H2(g) ® N2O(g) + H2O(g) SLOW N2O(g) + H2(g) ® N2(g) + H2O(g) FAST If the rate law is found to be Rate = k[H2][NO]2, could this support the proposed mechanism? Does the rate law indicate that the reaction is termolecular?
The experimental rate law for the reaction 2H2(g) + 2 NO(g) → N2(g) +2 H2O(g) is d[N2) = kods[Hz][NO] Below is a proposed mechanism: H2(g) + NO(g) + NO(g) = N2O(g) + H2O(g) H2(g) + N2O(g) = N2(g) + H2O(g) ki k2 (a) Under what conditions does this mechanism give the observed rate law? Express kobs in terms of the rate constants for the individual steps of the mechanism. A second proposed mechanism is: NO(g) + NO(g) = N2O2(g) N2O2(g)...
The rate law for the reaction 2H2(g) + 2NO(g) ----> N2(g) + 2H2O(g) is rate=k[H2][NO]2. What is the rate constant at 800 degrees C when [NO] = 0.050 M and [H2] = 0.010 M and the rate of the reaction is 1.5 M/s
1. a) Overall reaction: Rate = k[NO]^2 2NO(g)+H2(g)-> N2O(g)+H2O(g) propose a likely two step reaction mechanism for this reaction.
For the reaction, 2NO(g)+2H2(g)→N2(g)+2H2O(g), what direction will the reaction proceed if [NO]=7.9x10-3M, [H2]=0.25 M, [N2]=0.15 M, & [H2O]=0.13 M. (K=650) forward reverse the reaction has stopped the reaction is at equilibrium
The reaction 2 NO(g) + H2(g) --> N2O(g) + H2O(g) proceeds through the following mechanism: 2 NO(g) --> N2O2(g) N2O2(g) + H2(g) --> H2O(g) + N2(g) (b) What would the rate law be if the first step of this mechanism were rate-determining? Rate = k [NO] [H2]Rate = k [NO]2 [H2] Rate = k [NO] [H2]2Rate = k [NO]1/2 [H2] Rate = k [NO] [H2]1/2 Rate = k [NO]2 Rate = k [NO]2 [H2]1/2 Rate = k [NO]
Please answer each part with work shown. Thank you.
6. The following three mechanisms have been proposed for a particular reaction. Mechanism II Mechanism III Mechanisml H2 +NO-H2O+N (slow) N +NON2+0 (fast) O+H2-> H2O (fast) 2 NO-N202 (fast equilibrium) H2-N202-H20+ N3O (slow) H2+N20-H2O+N2 (fast) H2 + 2 NO- H2O+N2O (slow) N20+ H2N2+ H2O (fast) a) What is the overall reaction that each proposed mechanism supports? b) Calculate the ΔΗ'm for the overall reaction. c) For each mechanism, draw an energy...