CO(g) + H2O(g) ↔ CO2(g) +H2(g), Keq = 0.58
|
CO(g) |
H2O(g) |
↔ |
CO2(g) |
H2(g) |
|
|
Initial |
2.00 * 10-2 |
2.00 * 10-2 |
0 |
0 |
|
|
Change |
-x |
-x |
+x |
+x |
|
|
Equilibrium |
2.00 * 10-2 -x |
2.00 * 10-2 -x |
x |
x |
Keq = [CO][H2O] / [CO2][H2]
0.58 = (2.00 * 10-2-x)2 / x2
taking square root on both sides
0.762 = 0.02-x/x
0.762x =0.02-x
1.762x =0.02
X =0.02/1.762 =0.0113
So, at equilibrium
[CO]eq = 0.02-0.0113 =0.0087 mol/L
[H2O]eq = 0.02-0.0113 =0.0087 mol/L
[CO2]eq =0.0113 mol/L
[H2]eq = 0.0113 mol/L
For 20 L mixture, the number of moles
[CO] = 20* 0.0087 =0.174 moles
[H2O] = 20* 0.0087 = 0.174 moles
[CO2] = 20 * 0.0113 = 0.226 moles
[H2] = 20*0.0113 = 0.226 moles
www .locatoriamente INTERACTIVE EXAMPLE Solving an Equilibrium Problem (Involving a Linear Equation in x) Chapter 54...
INTERACTIVE EXAMPLE Solving an Equilibrium Problem (Involving a Linear Equation in x) The reaction CO(g) + H2O(g) + CO2(g) + H2(g) has an equilibrium constant K of 0.58 at 1000 °C. If a 20.0-L mixture of CO and H2O has a concentration of each of 6,00x10* moll, what amount (in moles) of each species will be present when the mixture reaches equilibrium? mol CO mol H20 mol CO2 mol H2 Submit